首页> 外文期刊>IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control >Dielectric spectroscopy of Nano BaTiO/sub 3/ confined in MCM-41 mesoporous molecular sieve materials
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Dielectric spectroscopy of Nano BaTiO/sub 3/ confined in MCM-41 mesoporous molecular sieve materials

机译:限制在MCM-41介孔分子筛材料中的纳米BaTiO / sub 3 /的介电谱

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摘要

Dielectric properties of barium titanate (BaTiO3) particles, synthesized directly in the pores of MCM-41 materials, have been investigated in the frequency range from 20 Hz to 1 MHz for temperature intervals from 100 K to 500 K. The dielectric spectra of BaTiO3 confined in these molecular sieves were compared with the results obtained from the investigation of pure MCM-41 materials. Obtained results confirmed successful incorporation of BaTiO3 into porous matrix, but no phase transition from paraelectric to ferroelectric phase was observed due to the particle size being smaller than the critical size. Also, the overall dielectric response of investigated materials is strongly influenced by adsorbed water molecules
机译:直接在MCM-41材料的孔中合成的钛酸钡(BaTiO3)颗粒的介电性能已在20 Hz至1 MHz的频率范围内,温度范围为100 K至500 K的条件下进行了研究。将这些分子筛中的Mg与纯MCM-41材料的研究结果进行比较。获得的结果证实了成功地将BaTiO3掺入到多孔基质中,但是由于颗粒尺寸小于临界尺寸,因此未观察到从顺电相到铁电相的相变。而且,被研究材料的整体介电响应受吸附水分子的强烈影响

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