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Elastic, piezoelectric, and dielectric characterization of modified BiScO/sub 3/-PbTiO/sub 3/ ceramics

机译:改性BiScO / sub 3 / -PbTiO / sub 3 /陶瓷的弹性,压电和介电特性

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摘要

The perovskite solid solution system (1-x)BiScO/sub 3/-(x)PbTiO/sub 3/ represents an interesting new family of high-temperature piezoelectric materials. Compositions near the morphotropic phase boundary (x /spl sim/ 0.64) have been reported to have high Curie temperatures (T/sub c/ > 450/spl deg/C) and good piezoelectric coefficients (d/sub 33/ /spl sim/ 460 pC/N). In this work, manganese additions were used to improve the high-temperature electrical resistivity and RC time constant of compositions near the morphotropic phase boundary. The addition of manganese was found to shift T/sub C/ to slightly lower temperatures (442/spl deg/C and 456/spl deg/C for x = 0.64 and x = 0.66, respectively). The piezoelectric activities of the modified materials were found to be reduced slightly due to the hardening effect of manganese; however, the temperature stability and resistivity of the modified materials were significantly enhanced. In this paper we present, for the first time, a complete set of materials constants, including the elastic (s/sub ij/, c/sub ij/), piezoelectric (d/sub ij/, e/sub ij/, g/sub ij/, h/sub ij/), dielectric (/spl epsi//sub ij/, /spl beta//sub ij/), and electromechanical (k/sub ij/) coefficients and compare them to both unmodified 0.36BiScO/sub 3/-0.64PbTiO/sub 3/ and PZT5A ceramics.
机译:钙钛矿固溶体体系(1-x)BiScO / sub 3 /-(x)PbTiO / sub 3 /代表了一个有趣的高温压​​电材料新家族。据报道,在同相相界附近(x / spl sim / 0.64)的成分具有较高的居里温度(T / sub c /> 450 / spl deg / C)和良好的压电系数(d / sub 33 / / spl sim / 460 pC / N)。在这项工作中,锰的添加被用来改善高温相的电阻率和RC时间常数的组成相相界附近。发现锰的添加将T / sub C /转移到稍低的温度(对于x = 0.64和x = 0.66,分别为442 / spl deg / C和456 / spl deg / C)。发现由于锰的硬化作用,改性材料的压电活性略有降低。然而,改性材料的温度稳定性和电阻率显着提高。在本文中,我们首次展示了一整套材料常数,包括弹性(s / sub ij /,c / sub ij /),压电(d / sub ij /,e / sub ij /,g / sub ij /,h / sub ij /),介电系数(/ spl epsi // sub ij /,/ spl beta // sub ij /)和机电系数(k / sub ij /),并将它们与未经修改的0.36进行比较BiScO / sub 3 / -0.64PbTiO / sub 3 /和PZT5A陶瓷。

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