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Thermal Conductivity of Sn-SnTe Alloys

机译:SN-SNTE合金的导热系数

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摘要

Alloys between tin and tin telluride have been prepared and their thermal conductivity has been measured in the temperature range ~90–300 K. We have determined the lattice (χ_(l)) and electron (χ_(el)) contributions to the thermal conductivity of the alloys and their thermal resistivity due to structural defects (Sn vacancies and defects). We assume that, at low excess Sn concentrations, Sn atoms form electroneutral complexes with Sn vacancies, leading to a reduction in χ_(l)and χ_(el). At high concentrations, Sn atoms fill vacancies, leading to an increase in χ_(l).
机译:已经制备了锡和锡碲化锡之间的合金,并在温度范围内测量了其导热率〜90-300k。我们已经确定了晶格(χ(L))和电子(χ(el))对导热率的贡献由结构缺陷(Sn空位和缺陷)引起的合金及其热阻率。我们认为,在低过量的Sn浓度下,Sn原子与SN空位形成电力络合物,导致χ_(l)和χ_(el)减少。在高浓度下,Sn原子填补空缺,导致χ_(l)增加。

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