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首页> 外文期刊>Inorganic materials >Phase Equilibria in the Pseudoternary System Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6
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Phase Equilibria in the Pseudoternary System Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6

机译:伪三元系Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6中的相平衡

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摘要

Phase equilibria in the Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6 system have been studied by differential thermal analysis, X-ray diffraction, scanning electron microscopy, and emf measurements on concentration cells with Ag_4RbI_5 as a solid electrolyte. We have mapped out the T-x phase diagram of the constituent binary system Ag_8GeSe_6-Ag_8SnSe_6, those of two mutually perpendicular sections, and the liquidus projection. The two crystalline phases of the constituent selenides Ag_8GeSe_6 and Ag_8SnSe_6 have been shown to form a continuous series of solid solutions. The Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6 system is a pseudoternary section through the quaternary system Ag-Ge-Sn-Se, and its phase diagram has a univariant eutectic.
机译:通过差示热分析,X射线衍射,扫描电子显微镜和在以Ag_4RbI_5为固体电解质的浓缩电池上进行电动势测量,研究了Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6体系中的相平衡。我们已绘制出组成二元系统Ag_8GeSe_6-Ag_8SnSe_6的T-x相图,两个相互垂直的截面的相图以及液相线投影。成分硒化物Ag_8GeSe_6和Ag_8SnSe_6的两个结晶相已显示形成一系列连续的固溶体。 Ag_2Se-Ag_8GeSe_6-Ag_8SnSe_6系统是四元系统Ag-Ge-Sn-Se的伪三元截面,其相图具有单变量共晶。

著录项

  • 来源
    《Inorganic materials》 |2014年第10期|981-986|共6页
  • 作者单位

    Ganja State University, pr. shakha Ismaila Khatai 187, Ganja, AZ 1000 Azerbaijan;

    Baku State University, ul. Khalilova 23, Baku, AZ 1148 Azerbaijan;

    Ganja State University, pr. shakha Ismaila Khatai 187, Ganja, AZ 1000 Azerbaijan;

    Ganja State University, pr. shakha Ismaila Khatai 187, Ganja, AZ 1000 Azerbaijan;

    Baku State University, ul. Khalilova 23, Baku, AZ 1148 Azerbaijan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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