Preparation of Nanocrystalline Ti, Mn, Co, Fe, and Zn Oxides via Heat Treatment in Aqueous Solutions

D. G. Kleshchev

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Preparation of Nanocrystalline Ti, Mn, Co, Fe, and Zn Oxides via Heat Treatment in Aqueous Solutions

机译：水溶液中热处理制备纳米晶的Ti，Mn，Co，Fe和Zn氧化物

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Crystallization, coalescence, chemical reactions, and phase transformations in disperse systems based on hydrous Ti, Mn, Co, Fe, and Zn oxides during heat treatment in solutions of various ionic compositions are analyzed. The results indicate that the transformations in disperse systems follow the dissolution-precipitation mechanism and are accompanied by mass transfer between the solid phase and solution. Reactions are considered, using iron(III) oxyhydroxides as an example, that occur at the solution-crystal interface, and the possible compositions of crystal-forming complexes and the elementary reactions involved in the incorporation of the complexes into different faces of growing crystals of the equilibrium phase are established.

机译：分析了在各种离子组成的溶液中进行热处理时，基于含水Ti，Mn，Co，Fe和Zn氧化物的分散体系中的结晶，聚结，化学反应和相变。结果表明，分散体系中的转变遵循溶解-沉淀机理，并伴随着固相和溶液之间的传质。以氢氧化铁（III）为例，考虑了发生在溶液-晶体界面的反应，以及可能形成晶体的配合物的组成以及将配合物掺入到正在生长的晶体的不同面上所涉及的基本反应。建立平衡阶段。

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来源
《Inorganic materials》 |2005年第1期|p.42-49|共8页
作者
D. G. Kleshchev;
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作者单位

South Ural State University, pr. Lenina 76, Chelyabinsk, 454080 Russia;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类工程材料学;
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Preparation of Nanocrystalline Ti, Mn, Co, Fe, and Zn Oxides via Heat Treatment in Aqueous Solutions

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