Chemical Equilibria in Hydrolysis of Germanium Tetrachloride and Arsenic Trichloride

V.A. Efremov; V.N. Potolokov; S.V. Nikolashin

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Chemical Equilibria in Hydrolysis of Germanium Tetrachloride and Arsenic Trichloride

机译：四氯化锗和三氯化砷水解中的化学平衡

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The chemical equilibria in the hydrolysis of high-purity germanium tetrachloride and arsenic trichloride at low water concentrations were studied by IR spectroscopy. The equilibrium constant of AsCl_3 hydrolysis was shown to correlate with the activity coefficient of AsCl_3. The equilibrium constants and thermo- dynamic characteristics of GeCl_4 and AsCl_3 hydrolysis in CCl_4 were calculated for the temperature range 283- 333 K.

机译：通过红外光谱研究了低水浓度下高纯度四氯化锗和三氯化砷的水解过程中的化学平衡。结果表明，AsCl_3水解的平衡常数与AsCl_3的活性系数相关。计算了在283-333 K温度范围内，GeCl_4和AsCl_3在CCl_4中水解的平衡常数和热力学特征。

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《Inorganic materials》 |2002年第8期|p.847-853|共7页
作者
V.A. Efremov; V.N. Potolokov; S.V. Nikolashin;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类工程材料学;
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Chemical Equilibria in Hydrolysis of Germanium Tetrachloride and Arsenic Trichloride

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