Phase Transformations and Melt Structure of Calcium Metasilicate

Yu. K. Voronko; A.A. Sobol; S.N. Ushakov

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Phase Transformations and Melt Structure of Calcium Metasilicate

机译：偏硅酸钙的相变和熔体结构

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The β→α phase transition, melting, crystalliztion, and vitrification of calcium metasilicate were studied by high-temperature Raman scattering spectroscopy. The results demonstrate that, in the course of melting, the [Si_3O_9] metasilicate rings, which form the structural basis of the α phase, transform mainly into [SiO_3]_∞ anions. The structural similarity or dissimilarity of the CaO·SiO_2 melt to crystalline phases is shown to have a crucial effect on its crystallization/vitrification behavior.

机译：通过高温拉曼散射光谱研究了偏硅酸钙的β→α相变，熔融，结晶和玻璃化。结果表明，在熔融过程中，形成α相结构基础的[Si_3O_9]硅酸盐环主要转变为[SiO_3]_∞阴离子。 CaO·SiO_2熔体与结晶相的结构相似性或不相似性显示出对其结晶/玻璃化行为的关键影响。

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《Inorganic materials》 |2002年第8期|p.825-830|共6页
作者
Yu. K. Voronko; A.A. Sobol; S.N. Ushakov;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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正文语种 eng
中图分类工程材料学;
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Phase Transformations and Melt Structure of Calcium Metasilicate

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