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Mechanochemical Synthesis of Metastable Solid Solutions: Phase Composition and Microstructure Evolution

机译:亚稳固溶体的机械化学合成:相组成和微观结构演变

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摘要

The formation of Cu-Sn, Cu-In, Ni-Sn, and Ni-In supersaturated solid solutions during mechanochemical synthesis was studied. It was found that, in the process of synthesis, intermetallic compounds were formed first. Electron-microscopic examination revealed the presence of stacking faults and microstrains nonuniformly distributed in the initial stages of mechanochemical synthesis. Further mechanical activation makes the microstrian distribution more uniform. The microstructure of the metastable solid solutions is well described by models taking into account the major types of structural imperfection-second-order microstrains and deformation stacking faults.
机译:研究了机械化学合成过程中Cu-Sn,Cu-In,Ni-Sn和Ni-In过饱和固溶体的形成。发现在合成过程中,首先形成金属间化合物。电子显微镜检查显示在机械化学合成的初始阶段存在堆垛层错和不均匀分布的微应变。进一步的机械活化使微条纹分布更均匀。亚稳态固溶体的微观结构可以通过考虑结构缺陷的主要类型(二阶微应变和变形堆积断层)很好地描述。

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