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Comparative Study of Three Cathodic Electron Acceptors on the Performance of Medatiorless Microbial Fuel Cell

机译:三种阴极电子受体对无介质微生物燃料电池性能的比较研究

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摘要

Microbial Fuel Cells (MFC) are capable of converting the chemical energy stored in the chemical compounds in a biomass to electrical energy with the aid of microorganisms. A better understanding of the relationship between the microbiological and electrical aspects of fuels cells is needed prior to successful MFC application. MFC constructed employing low-cost materials (salt bridge, graphite electrodes) without addition of any toxic mediators and using glucose (3 g L~(-1)) as substrate and three different electron acceptors potassium permanganate (KMnO_4), potassium ferricyanide (K_3[Fe(CN)_6]) and potassium dichromate (K_2Cr_2O_7) in the cathode chamber without pH adjustment was assessed in the present study. The results showed that MFC performance with KMnO_4 was superior than K_3[Fe(CN)_6] and K_2Cr_2O_7. Maximum voltage generation (OCV) and power density for KMnO_4 were 1.04 V and 7.29 mW m~(-2). Performance of MFC with K_3[Fe(CN)_6] and K_2Cr_2O_7 was much lower with a OCV and power density of 0.71 V; 0.92 mW m~(-2) and 0.56 V; 0.79 mW mm~(-2), respectively. Demonstrating that KMnO_4 can be used as an effective cathodic electron acceptor to enhance power output on MFC.
机译:微生物燃料电池(MFC)能够借助微生物将存储在生物质中的化合物中的化学能转化为电能。在成功应用MFC之前,需要更好地了解燃料电池的微生物学和电学方面之间的关系。 MFC采用低成本材料(盐桥,石墨电极)而没有添加任何有毒介质,并使用葡萄糖(3 g L〜(-1))作为底物和三种不同的电子受体高锰酸钾(KMnO_4),铁氰化钾(K_3)构造而成在本研究中评估了未经pH调节的阴极室中的[Fe(CN)_6])和重铬酸钾(K_2Cr_2O_7)。结果表明,KMnO_4的MFC性能优于K_3 [Fe(CN)_6]和K_2Cr_2O_7。 KMnO_4的最大电压产生(OCV)和功率密度分别为1.04 V和7.29 mW m〜(-2)。 OCV和功率密度为0.71 V时,使用K_3 [Fe(CN)_6]和K_2Cr_2O_7的MFC的性能要低得多。 0.92 mW m〜(-2)和0.56 V;分别为0.79 mW mm〜(-2)证明KMnO_4可以用作有效的阴极电子受体,以增强MFC上的功率输出。

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    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Botanica, Universidad Autonoma Agraria Antonio Narro, Calzada Antonio Narro 1923, Buenavista, Saltillo, Coahuila, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

    Departamento de Biotecnologia, Facultad de Ciencias Quimicas, Universidad Autonoma de Coahuila, Boulevard V. Carranza e Ing. J. Cardenas Valdes, Col. Republica Oriente, Saltillo, Coahuila, C.P. 25280, Mexico;

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  • 正文语种 eng
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  • 关键词

    cathodic electron acceptor; electrical energy; microbial fuel cell; potassium permanganate; power density; voltage;

    机译:阴极电子受体电能;微生物燃料电池高锰酸钾;功率密度电压;

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