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Hyphenated and non-hyphenated chromatographic techniques for trace level explosives in water bodies - a review

机译:联用和非联用色谱技术用于水体中痕量炸药的综述

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摘要

Explosives are a class of xenobiotic, which pose a permanent and increasing concern on human and ecosystem health. These chemicals are highly toxic, some carcinogenic, and their detection in rural areas, surrounding military bases and weapon training facilities, became imperious. Quality of potable water particularly in rural areas, where wells are the primary water sources, is of great importance. More effective ways of extraction with less solvent consumption, coupled with chromatographic separation and mass spectrometry/ultraviolet detection techniques, are needed to quantify these trace level hazardous compounds at sub-ppb levels. The ultimate scope of measuring the concentration for these environmental contaminants is to build effective strategies for site protection, remediation and removal. This complex and original review brings together a vast amount of published work on conventional and modern explosives extraction approaches and their means of identification and quantification by hyphenated chromatographic techniques. With a strong focus on aqueous sample preparation and a multitude of analysis methods presented, this paper enables the researcher to a good assessment on past, present and future aspects. Latest progress in the high-resolution instrumentation is also briefly discussed.
机译:炸药是一类异种生物,对人类和生态系统的健康提出了永久性的关注。这些化学物质剧毒,有致癌性,因此在农村地区,周围的军事基地和武器训练设施中进行检测变得势在必行。饮用水的质量非常重要,特别是在农村地区,那里的水是井的主要水源。需要更有效的萃取方法和更少的溶剂消耗,再加上色谱分离和质谱/紫外检测技术,以定量这些痕量级有害化合物(低于ppb级)。测量这些环境污染物浓度的最终范围是建立有效的现场保护,修复和清除策略。这份复杂而原始的评论汇集了有关常规和现代炸药提取方法及其通过联用色谱技术鉴定和定量化手段的大量已发表工作。本文着重于水溶液样品的制备和多种分析方法,使研究人员能够对过去,现在和将来的方面进行良好的评估。还简要讨论了高分辨率仪器的最新进展。

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