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Production and characterization of biodiesel from Eriobotrya Japonica seed oil: an optimization study

机译:Eriobotrya Japonica籽油生产和表征生物柴油的优化研究

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Biodiesel is now-a-days recognized as a real potential alternative to petroleum-derived diesel fuel due to its number of desirable characteristics. However, its higher production cost resulting mainly due to use of costly food-grade vegetable oils as raw materials is the major barrier to its economic viability. Present work is an attempt to explore the potential of Eriobotrya japonica seed oil for the synthesis of biodiesel using alkali-catalyzed transesterification. Optimization of production parameters, namely molar ratio of alcohol to oil, amount of catalyst, reaction time and temperature, was carried out using Taguchi method. Fatty acid composition of both oil and biodiesel was determined using GC and H-1 NMR. Alcohol to oil molar ratio of 6: 1, catalyst amount of 1% wt/wt, 2 h reaction time and 50 degrees C reaction temperature were found to be the optimum conditions for obtaining 94.52% biodiesel. Highest % contribution was shown by the 'amount of catalyst' (67.32%) followed by molar ratio of alcohol to oil (25.51%). Major fuel properties of E. japonica methyl esters produced under optimum conditions were found within the specified limits of ASTM D6751 for biodiesel, hence it may be considered a prospective substitute of petro-diesel.
机译:由于生物柴油的许多理想特性,如今已被公认为是石油衍生柴油燃料的真正潜在替代品。然而,其较高的生产成本主要是由于使用昂贵的食品级植物油作为原料,这是其经济可行性的主要障碍。当前的工作是尝试探索日本rio种子油在使用碱催化的酯交换反应合成生物柴油中的潜力。使用Taguchi方法优化生产参数,即醇与油的摩尔比,催化剂的量,反应时间和温度。使用GC和H-1 NMR测定了油和生物柴油中的脂肪酸组成。发现醇与油的摩尔比为6∶1,催化剂量为1%wt / wt,反应时间为2h,反应温度为50℃是获得94.52%生物柴油的最佳条件。 “催化剂用量”(67.32%)和其次的醇与油摩尔比(25.51%)显示出最高的%贡献率。发现在最佳条件下生产的日本粳稻甲酯的主要燃料特性在ASTM D6751对生物柴油的规定限制内,因此可以认为它是石油柴油的潜在替代品。

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