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Ammonia absorption in ionic liquids-based mixtures in plate heat exchangers studied by a semi-empirical heat and mass transfer framework

机译:半经验传热传质框架研究板式换热器中离子液体基混合物中的氨吸收

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摘要

Unfavorable transport properties have always been pointed out as the key factors that hinder the application of ammonia/ionic liquids (NH3/ILs) in absorption cycles, while heat and mass transfer of these new fluids in components have been rarely reported. In this study, a corrugated plate heat exchanger is selected as the geometry for exploring the absorption of NH3 in the proposed NH3/ILs working fluids. The process is studied making use of a semi-empirical framework: experimental data is needed to determine unknown information of heat and mass transfer, and a numerical model is developed making use of frequently applied theories. In addition, relevant transport properties of the NH3/ILs working fluids are modeled based on collected experimental data. The proposed model is used to study the heat and mass transfer performance during the absorption of NH3 vapor into NH3/ILs fluids. Distribution of local parameters and overall heat and mass transfer characteristics are obtained. The performance of absorption of NH3 into different working fluids is investigated as well. The overall heat transfer coefficient is found around 1.4 kW/(m(2).K) for the most promising working fluid NH3/[emim][SDI]. (C) 2019 The Authors. Published by Elsevier Ltd.
机译:一直以来,人们都指出不利的运输性能是阻碍氨/离子液体(NH3 / ILs)在吸收循环中应用的关键因素,而这些新液体在部件中的传热和传质却鲜有报道。在这项研究中,选择波纹板式换热器作为几何结构,以探索拟议的NH3 / ILs工作流体中NH3的吸收。使用半经验框架对过程进行了研究:需要实验数据来确定未知的传热和传质信息,并使用常用的理论开发数值模型。此外,基于收集的实验数据对NH3 / ILs工作流体的相关传输特性进行了建模。所提出的模型用于研究将NH3蒸气吸收到NH3 / ILs流体中的传热和传质性能。获得局部参数的分布以及总的传热和传质特性。还研究了NH3吸收到不同工作流体中的性能。对于最有前途的工作流体NH3 / [emim] [SDI],发现总传热系数约为1.4 kW /(m(2).K)。 (C)2019作者。由Elsevier Ltd.发布

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