首页> 外文期刊>International Journal of Heat and Mass Transfer >Transient modeling of heat, mass and momentum transfer of an evaporating cerium nitrate solution droplet with a surrounding shell in a rf thermal argon-oxygen plasma under reduced pressure
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Transient modeling of heat, mass and momentum transfer of an evaporating cerium nitrate solution droplet with a surrounding shell in a rf thermal argon-oxygen plasma under reduced pressure

机译:减压条件下射频热氩氧等离子体中蒸发的硝酸铈溶液小滴与周围壳体的热,质量和动量传递的瞬态模型

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摘要

A model was developed to study the evaporation of a solution droplet surrounded by a porous crust in a stagnant rf Ar-O_2 thermal plasma under reduced pressure. This model considered a three phase system: a liquid core of dissolved Ce(NO_3)_3 • 6H_2O in water, a porous crust of homogeneously precipitated spherical crystals of equal size containing water vapor, and an Ar-O_2 plasma under reduced pressure. The model was solved considering a receding solution/crust interface in an ALE frame using temperature and composition dependant thermophysical properties. Darcy flow with a Knudsen correction to account for the gaseous flow through a porous media composed of nano-sized crystals was employed. The strength of the solid/liquid interface was calculated by computing the strength of liquid bridges formed at this interface. This value was compared to the pressure build-up caused by solvent evaporation and the point of crust breakage was determined at different operating conditions. The effects of plasma gas temperature, pressure and composition, droplet size, size of precipitated crystals and crust porosity on crust bursting were studied. The results showed that crust bursting occurred for all the conditions analyzed and that plasma temperature, droplet size and the size of the precipitated crystals had a significant effect on pressure build-up.
机译:开发了一个模型来研究在停滞的rf Ar-O_2热等离子体中在减压下被多孔壳包围的溶液液滴的蒸发。该模型考虑了一个三相系统:在水中溶解了Ce(NO_3)_3•6H_2O的液核,包含水蒸气的等大小的均匀沉淀的球形晶体的多孔硬壳,以及在减压下的Ar-O_2等离子体。考虑温度和成分相关的热物理特性,考虑ALE框架中的后退溶液/结壳界面来求解模型。采用达克西修正值的达西流,以说明通过纳米级晶体组成的多孔介质的气体流。固/液界面的强度通过计算在该界面形成的液桥的强度来计算。将该值与溶剂蒸发引起的压力增加进行比较,并确定在不同操作条件下的结壳破裂点。研究了等离子气体温度,压力和组成,液滴大小,析出晶体的大小和地壳孔隙度对地壳破裂的影响。结果表明,在所分析的所有条件下均会发生结壳破裂,并且等离子体温度,液滴尺寸和沉淀晶体的尺寸对压力累积有显着影响。

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