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首页> 外文期刊>International journal of hydrogen energy >Synthesis and electrochemical characterization of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ) / Ce_(0.9)Gd_(0.1)O_(1.95) co-electrospun nanofiber cathodes for intermediate-temperature solid oxide fuel cells
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Synthesis and electrochemical characterization of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ) / Ce_(0.9)Gd_(0.1)O_(1.95) co-electrospun nanofiber cathodes for intermediate-temperature solid oxide fuel cells

机译:LA_(0.6)SR_(0.4)CO_(0.2)FE_(0.8)O_(3-δ)/ CE_(0.9)GD_(0.1)O_(1.95)共电扫描纳米纤维阴极的合成和电化学表征用于中间温度固体 氧化物燃料电池

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Synthesis and electrochemical characterization of composite cathodes, formed from a mixture of La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) and Ce0.9Gd0.1O1.95 (GDC) nanofibers, is reported. The electrodes are obtained by simultaneous electrospinning of the two precursor solutions, using apparatus equipped with two spinnerets working in parallel. Results of electrochemical testing carried out through electrochemical impedance spectroscopy (EIS) are presented and discussed. The results suggest that the electrochemical reaction takes place in an electrode region close to the electrode/current collector interface and that the oxygen ions then flow along the ionic conducting path of the GDC fibers. At 650 degrees C, the polarization resistance is R-p = 5.6 U cm(-2), in line with literature values reported for other IT-SOFC cathodes. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:报道了由LA0.6SR0.4CO0.2FE0.8O3-DERTA(LSCF)和CE0.9GD0.1O1.95(GDC)纳米纤维的混合物形成的复合阴极的合成和电化学表征。 通过配备有两个平行工作的两个喷丝头的装置,通过同时静电地纯化电极。 提出和讨论了通过电化学阻抗光谱(EIS)进行的电化学测试的结果。 结果表明,电化学反应在靠近电极/集电器界面的电极区域中进行,并且氧离子然后沿着GDC纤维的离子传导路径流动。 在650℃下,偏振电阻是R-P = 5.6u cm(-2),其与其他IT-SOFC阴极报道的文献值相同。 (c)2020氢能源出版物LLC。 elsevier有限公司出版。保留所有权利。

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