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首页> 外文期刊>International journal of hydrogen energy >Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water
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Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water

机译:葡萄糖制氢作为超临界水中气化生物质的模型化合物

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Thermochemical gasification of biomass has been identified as a possible system for producing renewable hydrogen. A continuous tubular supercritical water gasification system is under development that can be used for solution or slurry materials gasification without drying. A unique feature of this system is its ability to realize the overall high-pressure continuous reaction by operating the valves. By the use of this system, designed for temperatures up to 923.15 K and pressures up to 35 MPa, glucose, as a model compound of biomass, was gasified in supercritical water at a series of temperature and pressure during different resident times to form a product gas composed of H_2, CO, CH_4, CO_2, and a small amount of C_2H_4 and C_2H_6. Glucose at low concentrations (ca. 0.1 M) can be completely gasified in 923.15 K, 25 MPa, and 3.6 min resident time and no char or tar was observed. Consequently, we adopted these conditions as baseline reaction conditions for the following glucose concentration, alkali addition and reactor tube diameter effect studies. The raw biomass feedstock of sawdust with some CMC was also gasified in this system, the gasification efficiency in excess of 95% was reached.
机译:生物质的热化学气化已被确定为生产可再生氢的可能系统。正在开发一种连续的管状超临界水气化系统,该系统可用于溶液或浆状物料的气化而无需干燥。该系统的独特功能是通过操作阀门实现整体高压连续反应的能力。通过使用设计用于高达923.15 K的温度和高达35 MPa的压力的系统,葡萄糖作为生物质的模型化合物,在不同的停留时间,一系列温度和压力下,在超临界水中以一系列温度和压力气化,从而形成一种产品气体由H_2,CO,CH_4,CO_2和少量的C_2H_4和C_2H_6组成。低浓度(约0.1 M)的葡萄糖可以在923.15 K,25 MPa和3.6分钟的停留时间内完全气化,没有观察到焦炭或焦油。因此,我们将这些条件作为基线反应条件,用于随后的葡萄糖浓度,碱添加和反应器管直径效应研究。在该系统中,还对带有某些CMC的木屑原料生物质原料进行了气化,气化效率超过了95%。

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