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Behaviour of radioactive iodine and bromine from aqueous solutions on the ion-exchange resin DuoliteA-113

机译:水溶液中放射性碘和溴在离子交换树脂DuoliteA-113上的行为

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摘要

The iodide and bromide forms of the ion exchange resin Duolite A-113 were equilibrated separately with respectively labelled iodide and bromide ion solutions of different concentrations, varying from 0.005 M to 0.100 M in the temperature range of 26.0℃ to 43.0℃. The distribution coefficient K_d values calculated for iodide and bromide ion exchanges increase with the ionic concentration of the external solution; however, with a rise in temperature, the K_d values calculated were found to decrease. Also, the K_d values were higher for iodide exchanges than for bromide exchanges.
机译:将离子交换树脂Duolite A-113的碘化物和溴化物形式分别与标记的不同浓度的碘化物和溴化物离子溶液(在26.0℃至43.0℃的温度范围为0.005 M至0.100 M)进行平衡。计算出的碘离子和溴离子交换的分布系数K_d值随外部溶液的离子浓度而增加;然而,随着温度的升高,发现计算出的K_d值降低。同样,碘化物交换的K_d值高于溴化物交换的K_d值。

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