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Curing kinetics, mechanical properties and thermomechanical analysis of carbon fiber/epoxy resin laminates with different ply orientations

机译:用不同帘布层定位碳纤维/环氧树脂层压板的固化动力学,力学性能和热机械分析

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摘要

A carbon fiber/epoxy resin prepreg was tested by DSC, and the phenomenological nth-order and autocatalytic reaction curing kinetic models of the prepreg were established. On this basis, the optimum curing process of the prepreg was obtained. In addition, in order to explore the effect of ply parameters on the mechanical properties of the laminates, the thermomechanical and mechanical properties of the laminates of [0](10), [+ 45/ - 45](5s) and [0/90](5s), prepared by compression molding, were investigated. The results show that the autocatalytic reaction model agrees well with the DSC curves obtained from the experimental data. The curing process of the carbon fiber/epoxy resin prepreg is 130 degrees C /60 + 160 degrees C/30 min. The flexural and impact strength of [0](10) laminates are higher than that of [+ 45/ - 45](5s) and [0/90](5s) laminates. The glass transition temperature (T-g) of the laminates is 142-146 degrees C, and the loss factor of [0](10) laminate is significantly higher than that of [+ 45/ - 45](5s) and [0/90](5 s) laminates. The great differences in the mechanical properties of the laminates are mainly due to the different amounts of 0 degrees fibers, which lead to the different bearing and deformation capacity of the laminates under external force. Graphic abstract
机译:通过DSC测试碳纤维/环氧树脂预浸料,并建立了预浸料坯的现象学Nth阶和自催化反应固化动力学模型。在此基础上,获得预浸料的最佳固化过程。另外,为了探讨帘布层参数对层压板的机械性能的影响,[0](10),[+ 45 / - 45](5s)和[0 /的层压板的热机械和机械性能研究了通过压缩成型制备的90](5S)。结果表明,自催化反应模型与从实验数据中获得的DSC曲线吻合良好。碳纤维/环氧树脂预浸料坯的固化过程是130℃/ 60 + 160℃/ 30分钟。 [0](10)层压物的弯曲和冲击强度高于[+ 45 / - 45](5s)和[0/90](5s)层压材料。层压板的玻璃化转变温度(Tg)为142-146℃,[0](10)层压体的损耗因子显着高于[+ 45 / - 45](5s)和[0/90] ](5秒)层压板。层压板的机械性能的差异主要是由于0度纤维的量不同,这导致了外力下层压板的不同轴承和变形容量。图形摘要

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