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In situ Synthesis of Nano-sized ZrC and Its Formation Mechanism by Combustion Synthesis from Zr-C-Cu System

机译:Zr-C-Cu体系燃烧合成原位纳米ZrC及其形成机理

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摘要

Nano-sized ZrC was prepared by combustion synthesis (CS) from Cu-Zr-C elemental powder mixtures. The ZrC particle size greatly decreased from about 10 μm with an irregular shape in free Cu addition to nano-meter order with a nearly spherical shape in Cu addition ranging from 10 wt.% to 30 wt.%. The formation mechanism of the nano-sized ZrC was discussed. The low dissolubility of C into Cu melt may greatly inhibit the growth of product ZrC, resulting in formation of ZrC particles as fine as nano-sized C. Melting of metallic Cu plays an important role in the formation mechanism of the nano-sized ZrC.
机译:纳米ZrC是通过燃烧合成(CS)从Cu-Zr-C元素粉末混合物中制备的。 ZrC粒径从大约10μm(游离铜添加不规则形状)大大减小到纳米级,Cu添加量从10 wt。%到30 wt。%几乎呈球形。讨论了纳米ZrC的形成机理。 C在Cu熔体中的低溶解性可能会极大地抑制产物ZrC的生长,导致形成与纳米级C一样细的ZrC颗粒。金属Cu的熔化在纳米ZrC的形成机理中起着重要作用。

著录项

  • 来源
    《ISIJ international》 |2011年第10期|p.1576-1579|共4页
  • 作者单位

    School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240 PR China;

    School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240 PR China;

    School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240 PR China;

    School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240 PR China;

    School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai, 200240 PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Cu; ZrC; formation mechanism; nanomaterials;

    机译:铜ZrC;形成机理纳米材料;

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