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Mechanism of Dioxins/Furans Formation at High Temperature in Combustion Processes

机译:燃烧过程中高温下二恶英/呋喃形成的机理

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To understand the mechanism of toxic dioxins/furans (Dioxins) formation in incineration processes, the combustion experiments were carried out with an electric furnace in laboratory scale at 1073 K using mainly the powder of regent grade polyvinyl chloride (PVC powder) as a combustion material under a complete and an incomplete combustion conditions. In addition, the thermodynamic evaluations have been done on the formation and decomposition of Dioxins. Dioxins are formed even at the combustion temperature of 1073 K under the conditions in which the fly carbonaceous matters exist. It is supposed that Dioxins are mainly formed on the surface of the fly carbonaceous matters where high CO/CO_2 ratio is established. Dioxins' concentration is correlated with the number of the fly carbonaceous matters in an exhaust gas. The formation/suppression of Dioxins is dependent upon the amount of the fly carbonaceous matters remained in the exhaust gas from the combustion furnaces.
机译:为了了解焚化过程中有毒的二恶英/呋喃(二恶英)形成的机理,使用实验室规模的电炉在1073 K的温度下进行燃烧实验,主要使用摄政级别的聚氯乙烯粉末(PVC粉末)作为燃烧材料在完全和不完全燃烧条件下。另外,已经对二恶英的形成和分解进行了热力学评估。即使在存在飞碳质物质的条件下,即使在1073 K的燃烧温度下也会形成二恶英。据推测,二恶英主要形成在建立高CO / CO_2比的粉状碳质物质的表面上。二恶英的浓度与废气中的苍蝇含碳物质的数量有关。二恶英的形成/抑制取决于燃烧炉废气中残留的蝇状碳质物质的量。

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