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Copper-Holmium Alloy Film for Reliable Interconnects

机译:可靠互连的铜-合金膜

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摘要

We fabricate reliable interconnects via advanced barrierless metallization by cosputtering a pure copper (Cu) film with small amounts of holmium nitride (HoN_x) on a silicon (Si) substrate. No noticeable interaction occurs between the resulting Cu(HoN_x) film and the substrate even after heating at 660 ℃ for 1 h. The resistivity of the alloy film, which remains stable after five cycles of heating at 600 ℃ (total: 2.5 h), is high under the as-deposited condition, but decreases to ~3.0 μΩ cm after annealing. The leakage current of the alloy film is three times lower than that of the pure Cu film. The correlation between the leakage current and the time-dependent dielectric breakdown (TDDB) lifetime reveals that the alloy film has a TDDB lifetime of > 10 years. Furthermore, the alloy film adheres better to the Si substrate than does the pure Cu film. Our alloy film thus has improved features that are desirable for a reliable interconnect.
机译:我们通过在硅(Si)基板上共溅射纯铜(Cu)膜和少量氮化nitride(HoN_x)来通过先进的无障碍金属化工艺来制造可靠的互连。即使在660℃下加热1 h,所得的Cu(HoN_x)膜与基板之间也没有明显的相互作用。合金膜的电阻率在沉积条件下较高,在600℃加热五个循环(总计2.5 h)后仍保持稳定,但在退火后降低至约3.0μΩcm。合金膜的泄漏电流是纯铜膜的泄漏电流的三倍。泄漏电流与时间相关的介电击穿(TDDB)寿命之间的相关性表明,合金膜的TDDB寿命> 10年。此外,与纯Cu膜相比,合金膜更好地粘附到Si衬底上。因此,我们的合金膜具有可靠互连所需的改进功能。

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  • 来源
    《Japanese journal of applied physics》 |2010年第5issue3期|P.05FA03.1-05FA03.4|共4页
  • 作者单位

    Department of Environmental Engineering, Chin-Min Institute of Technology, Tou-Fen, Taiwan 351;

    Institute of Materials Engineering, National Taiwan Ocean University, Keelung, Taiwan 202;

    Graduate Institute of Materials Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan;

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