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首页> 外文期刊>Japanese journal of applied physics >Correlation between Segregation of Rare Earth Dopants in Melt Crystal Growth and Ceramic Processing for Optical Applications
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Correlation between Segregation of Rare Earth Dopants in Melt Crystal Growth and Ceramic Processing for Optical Applications

机译:熔体晶体生长中稀土掺杂的偏析与光学应用陶瓷加工之间的相关性

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摘要

The paper deals with segregation of rare earth doping cations in solid-state hosts. Increased concentration of Ce~(3+) and Nd~(3+) on the grain boundaries of transparent garnet optical ceramics was recently reported. These experimental results correlate well with low segregation coefficients of Ce~(3+) and Nd~(3+) large rare earth cations and the higher segregation coefficients for small rare earth cations like Yb~(3+) in the garnet structure observed in the melt crystal growth and thin film liquid phase epitaxy from flux. Thus, the segregation in solid-state grain growth is qualitatively similar to that observed in the melt/flux growth of the garnet single crystals. The data on segregation in the melt/flux crystal growth are widely available and can be used for preliminary estimation of the dopant distribution in the ceramics produced from the solid state. This information could help to predict distribution of doping cations in the solid state hosts that is important in development of uniform and highly efficient optical materials.
机译:本文研究了固态基质中稀土掺杂阳离子的离析。最近报道了在透明石榴石光学陶瓷的晶界上Ce〜(3+)和Nd〜(3+)的浓度增加。这些实验结果与Ce〜(3+)和Nd〜(3+)大稀土阳离子的低偏析系数以及石榴石结构中的Yb〜(3+)等小型稀土阳离子的较高偏析系数相关。熔体晶体的生长和薄膜液相外延起因。因此,固态晶粒生长中的偏析在质量上与石榴石单晶的熔体/熔剂生长中观察到的偏析相似。关于熔体/熔剂晶体生长中的偏析的数据是可广泛获得的,并且可用于初步估计由固态生产的陶瓷中的掺杂剂分布。该信息可以帮助预测掺杂剂在固态基质中的分布,这对开发均匀高效的光学材料非常重要。

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  • 来源
    《Japanese journal of applied physics》 |2010年第7issue1期|P.075601.1-075601.6|共6页
  • 作者单位

    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan;

    rnInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan Physical Chemistry of Luminescent Materials, University of Lyon, Claude Bernard University Lyon 1,UMR 5620 CNRS, Villeurbanne 69622, France;

    rnPhysical Chemistry of Luminescent Materials, University of Lyon, Claude Bernard University Lyon 1,UMR 5620 CNRS, Villeurbanne 69622, France University of Science and Technology of China, Hefei, Anhui 230026, China;

    rnInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan;

    rnInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan New Industry Creation Hatchery Center, Tohoku University, Sendai 980-8579, Japan;

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