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Leakage Current Properties of Cation-Substituted BiFeO_3 Ceramics

机译:阳离子取代的BiFeO_3陶瓷的漏电流特性

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摘要

Cation-doped BiFeO_3 ceramics were fabricated by sintering coprecipitated and calcined powders at 700-900℃ to study the effect of cation doping on the leakage current properties of the sintered samples. Among the dopants examined in this study, Ti~(4+), Sn~(4+), or Zr~(4+) doping was found to effectively reduce the leakage current of the samples. In particular, a marked decrease in the leakage current density was achieved at 10% Ti~(4+) doping, which also resulted in the structure change from rhombohedral to cubic. The codoping of Ti~(4+)/Zn~(2+) ions or Ti~(4+)/Ni~(2+) ions brought about a substantial reduction in the leakage current density of the bulk samples by about four or five orders of magnitude at a small doping amount of 2%. This can be explained by the combined effect of Ti~(4+) doping, which basically contributes to the decreased number of oxygen vacancies in the sample, and Zn~(2+) or Ni~(2+) doping, which might assist the homogeneous substitution of Ti~(4+) ions for the Fe~(3+) sites.
机译:通过在700-900℃下烧结共沉淀和煅烧的粉末,制备了阳离子掺杂的BiFeO_3陶瓷,以研究阳离子掺杂对烧结样品漏电流性能的影响。在这项研究中研究的掺杂物中,发现Ti〜(4 +),Sn〜(4+)或Zr〜(4+)掺杂可以有效降低样品的漏电流。特别地,在掺杂10%Ti〜(4+)时,漏电流密度显着降低,这也导致结构从菱形变为立方。 Ti〜(4 +)/ Zn〜(2+)离子或Ti〜(4 +)/ Ni〜(2+)离子的共掺杂使整体样品的漏电流密度显着降低了约4%或4%。在2%的少量掺杂下达到五个数量级。这可以通过Ti〜(4+)掺杂和Zn〜(2+)或Ni〜(2+)掺杂的组合效应来解释,这基本上有助于减少样品中的氧空位数量。 Ti〜(4+)离子对Fe〜(3+)位的均匀取代。

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  • 来源
    《Japanese journal of applied physics》 |2010年第9issue2期|p.09MB01.1-09MB01.6|共6页
  • 作者单位

    Division of Materials Chemistry, Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Kita-ku, Sapporo 060-8628, Japan;

    rnDivision of Materials Chemistry, Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Kita-ku, Sapporo 060-8628, Japan;

    rnDivision of Materials Chemistry, Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Kita-ku, Sapporo 060-8628, Japan;

    rnDepartment of Materials Science, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507, Japan;

    rnCeramics Research Laboratory, Nagoya Institute of Technology, 10-6-29 Asahigaoka, Tajimi, Gifu 507-0071, Japan;

    rnCeramics Research Laboratory, Nagoya Institute of Technology, 10-6-29 Asahigaoka, Tajimi, Gifu 507-0071, Japan;

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