Effect of Boric Acid Flux and Drying Control Chemical Additive on the Characteristics of Y_2O_3:Eu Phosphor Particles Prepared by Spray Pyrolysis

Hye Young Koo; Seo Hee Ju; Seung Kwon Hong; Dae Soo Jung; Yun Chan Kang; Kyeong Youl Jung

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Effect of Boric Acid Flux and Drying Control Chemical Additive on the Characteristics of Y_2O_3:Eu Phosphor Particles Prepared by Spray Pyrolysis

机译：硼酸通量和干燥控制化学添加剂对喷雾热解法制备Y_2O_3：Eu荧光粉颗粒特性的影响

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Y_2O_3:Eu phosphor particles with a spherical shape, a fine size, and high brightness under vacuum ultraviolet (VUV) illumination were prepared by spray pyrolysis. The polymeric precursors were needed to modify the spray solution to prepare spherical particles. The use of only flux with the polymeric precursors did not produce dense and spherical Y_2O_3:Eu particles; that is, the produced particles were very porous. The addition of both a drying control chemical additive (DCCA) and boric acid to a spray solution containing polymeric precursors was found to produce Y_2O_3:Eu phosphor particles with a dense structure while maintaining the spherical morphology. According to X-ray diffraction (XRD) analysis, the DCCA induced an enhancement of crystallinity. The use of boric acid flux improved the photoluminescence (PL) intensity under VUV illumination. In addition, the use of both boric acid flux and a DCCA with polymeric precursors further improved the PL intensity owing to the enhancement of the morphology and the crystallinity.

机译：通过喷雾热解制备了球形，细小，高亮度的Y_2O_3：Eu荧光粉。需要聚合物前体来改变喷雾溶液以制备球形颗粒。仅将助熔剂与聚合物前体一起使用不会产生致密且球形的Y_2O_3：Eu颗粒。即，产生的颗粒是非常多孔的。发现将干燥控制化学添加剂（DCCA）和硼酸两者都添加到含有聚合物前体的喷雾溶液中，可以产生具有致密结构的Y_2O_3：Eu荧光粉颗粒，同时保持球形形态。根据X射线衍射（XRD）分析，DCCA诱导了结晶度的提高。硼酸通量的使用改善了在VUV照射下的光致发光（PL）强度。另外，由于形态和结晶度的增强，硼酸助熔剂和DCCA与聚合物前体一起使用进一步改善了PL强度。

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《Japanese Journal of Applied Physics. Part 1, Regular Papers, Brief Communications & Review Papers》 |2006年第12期|p.9083-9087|共5页
作者
Hye Young Koo; Seo Hee Ju; Seung Kwon Hong; Dae Soo Jung; Yun Chan Kang; Kyeong Youl Jung;
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作者单位

Department of Chemical Engineering, Konkuk University, 1 Hwayang-dong, Gwangjin-gu, Seoul 143-701, Korea;

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原文格式 PDF
正文语种 eng
中图分类应用物理学;
关键词
phosphor; spray pyrolysis; photoluminescence;

机译：荧光粉;喷雾热解;光致发光;

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1. Gd_2O_3:Eu phosphor particles prepared from spray solution containing boric acid flux and polymeric precursor by spray pyrolysis [J] . Dae Soo Jung, Seung Kwon Hong, Hyo Jin Lee, Optical Materials . 2006,第5期

机译：GD_2O_3：通过喷雾热解含有硼酸通量和聚合物前体的喷雾溶液制备的EU磷光体颗粒
2. Effect of boric acid flux on the characteristics of (CeTb)MgAl_(11)O_(19) phosphor particles prepared by spray pyrolysis [J] . Dae Soo Jung, Seung Kwon Hong, Hyo Jin Lee Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2005,第1a2期

机译：硼酸通量对喷雾热解法制备（CeTb）MgAl_（11）O_（19）荧光粉颗粒特性的影响
3. Effects Of N, N-dimethylacetamide As Drying Control Chemical Additive On Characteristics Of Zn_2sio_4:mn,ba Phosphor Powders Prepared By Spray Pyrolysis [J] . Hye Young Koo, Sang Ho Lee, Yun Chan Kang Japanese journal of applied physics . 2008,第9issue1期

机译：N，N-二甲基乙酰胺作为干燥控制化学添加剂对喷雾热解Zn_2sio_4：mn，ba荧光粉性能的影响
4. Synthesis of Y_2O_3:Eu Phosphor Nanoparticles by Flame Spray Pyrolysis [C] . Xiao Qin, Yiguang Ju, Stefan Bernhard, 2005 NSTI Nanotechnology Conference and Trade Show(NSTI Nanotech 2005) vol.2 . 2005

机译：火焰喷涂热解法合成Y_2O_3：Eu荧光粉纳米粒子
5. Control of particle morphology and homogeneity during spray pyrolysis: Diffusion drying stage. [D] . Lin, Jui-Chen. 1999

机译：喷雾热解过程中颗粒形态和均质性的控制：扩散干燥阶段。
6. Optoelectronic characteristics of YAG phosphor-incorporated ZnO films deposited by ultrasonic spray pyrolysis [O] . Lung-Chien Chen, Chien-Chung Huang 2012

机译：超声喷涂热解沉积YAG掺磷的ZnO薄膜的光电特性
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Effect of Boric Acid Flux and Drying Control Chemical Additive on the Characteristics of Y_2O_3:Eu Phosphor Particles Prepared by Spray Pyrolysis

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