Substitution of α-azido ethers with Grignard reagents and its use in combinatorial chemistry

Mukulesh Baruah and Mikael Bols

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Substitution of α-azido ethers with Grignard reagents and its use in combinatorial chemistry

机译：Grignard试剂取代α-叠氮基醚及其在组合化学中的应用

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α-Azidobenzyl ethers were reacted with alkyl or arylGrignard reagents in toluene to produce α-alkylbenzyl orndiarylmethyl ethers in 82–94% yield. α-Azidobenzyl ethers were also reacted with multicomponent Grignardnreagents to produce libraries of α-alkylbenzyl ethers.

机译：α-叠氮基苄基醚与烷基或芳基格氏试剂在甲苯中反应生成α-烷基苄基正二芳基甲基醚，产率为82-94％。 α-叠氮基苄基醚也与多组分格氏试剂反应生成α-烷基苄基醚的库。

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《Journal of the Chemical Society, Perkin Transactions 1》 |2002年第4期|p.509-512|共4页
作者
Mukulesh Baruah and Mikael Bols;
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Department of Chemistry, University of Aarhus, Langelandsgade 140 Aarhus C, DK-8000,Denmark. E-mail: mb@kemi.aau.dk;

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1. Substitution of alpha-azido ethers with Grignard reagents and its use in combinatorial chemistry [J] . Baruah M., Bols M. Journal of the Chemical Society, Perkin Transactions 1 . 2002,第4期

机译：用格氏试剂取代α-叠氮基醚及其在组合化学中的应用
2. Two-and Three Dimensional Combinatorial Chemistry from Multicomponent Grignard Reagents [J] . Anne Bulow, Steffen Sinning, Ove Wiborg, Journal of combinatorial chemistry . 2004,第4期

机译：多组分格氏试剂的二维和三维组合化学
3. 1,4-Dioxane Adducts of Grignard Reagents: Synthesis, Ether Fragmentation Reactions, and Structural Diversity of Grignard Reagent/1,4-Dioxane Complexes [J] . Langer J, Krieck S, Fischer R, Organometallics . 2009,第19期

机译：格氏试剂的1,4-二恶烷加合物：格氏试剂/ 1,4-二恶烷配合物的合成，醚裂解反应和结构多样性
4. gamma-Selective Allylic Substitution Reaction with Grignard Reagents Catalyzed by Copper N-Heterocyclic Carbene Complexes [C] . Sentaro Okamoto, Satoshi Tominaga, Yukinao Oi, Symposium on Organometallic Chemistry . 2004

机译：γ-选择性烯丙基取代反应与铜正杂环碳络合物催化的格氏试剂
5. Porphyrins: A solvent free synthesis, combinatorial libraries, a solid phase synthesis, and towards a tetra-Grignard reagent. [D] . Gong, Xianchang. 2000

机译：卟啉：无溶剂合成，组合库，固相合成和四格氏试剂。
6. Two Palladium-Catalyzed Domino Reactions from One Set of Substrates/Reagents: Efficient Synthesis of Substituted Indenes and cis-Stilbenoid Hydrocarbons from the Same Internal Alkynes and Hindered Grignard Reagents [O] . Cheng-Guo Dong, Pik Yeung, Qiao-Sheng Hu -1

机译：从一组底物/试剂中进行两个钯催化的多米诺反应：从相同的内部炔烃和受阻的格氏试剂中高效合成取代的茚类和顺式-类苯乙烯烃
7. Chemistry of Nitrosoimines. XI. Reactions of 3-Substituted 2-Nitrosoimino-2,3-dihydrobenzothiazoles with Benzyl and Allylic Grignard Reagents [O] . Motoyuki Hisaoka, Kin-ya Akiba, Naoki Inamoto 1975

机译：亚硝基菊的化学。 XI。用苄基和烯丙基格氏试剂的3取代的2-亚硝基氨基-2,3-二氢苯基唑烷的反应

Substitution of α-azido ethers with Grignard reagents and its use in combinatorial chemistry

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