Ring-opening reactions of cyclopropanes. Part 7. Selenenylation and cyanoselenenylation of ethyl 2,2-dimethoxycyclopropanecarboxylates

M. Liliana Graziano M. Rosaria Iesce Flavio Cermola Giovanni Caputo and Fulvio De Lorenzo

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Ring-opening reactions of cyclopropanes. Part 7. Selenenylation and cyanoselenenylation of ethyl 2,2-dimethoxycyclopropanecarboxylates

机译：环丙烷的开环反应。第7部分。2,2-二甲氧基环丙烷甲酸乙酯的硒化和氰基烯化

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In the presence of TiCl4, allyllithium adds to tricarbonylchromium complexes of 2-arylidene-1-tetralone and 2-arylideneindan-n1-one (1a–c) to afford endo-1,2-adducts (2a–c) exclusively. Subsequent oxy-Cope rearrangement deliversnthe allyl group stereospecifically along the endo-face to the sterically hindered benzylic position of the metalcomplexednring.

机译：在存在TiCl4的情况下，烯丙基锂会添加到2-芳基-1-丁酮和2-芳基茚满-n1-one（1a–c）的三羰基铬配合物中，专门提供内1,2-加合物（2a–c）。随后的oxy-Cope重排将烯丙基沿着内表面立体定向地传递到金属络合环的位阻苄基位置。

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《Journal of the Chemical Society, Perkin Transactions 1》 |2002年第6期|p.664-668|共5页
作者
M. Liliana Graziano M. Rosaria Iesce Flavio Cermola Giovanni Caputo and Fulvio De Lorenzo;
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Division of Organic Chemistry (Synthesis), National Chemical Laboratory, Pune-411 008,India;

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1. Ring-opening reactions of cyclopropanes. Part 7. Selenenylation and cyanoselenenylation of ethyl 2,2-dimethoxycyclopropanecarboxylates [J] . M. Liliana Graziano M. Rosaria Iesce Flavio Cermola Giovanni Caputo and Fulvio De Lorenzo Journal of the Chemical Society, Perkin Transactions 1 . 2002,第6期

机译：环丙烷的开环反应。第7部分。2,2-二甲氧基环丙烷甲酸乙酯的硒化和氰基烯化
2. Ring-opening reactions of cyclopropanes. Part 7. Selenenylation and cyanoselenenylation of ethyl 2,2-dimethoxycyclopropanecarboxylates [J] . Graziano ML., Iesce MR., Cermola F., Journal of the Chemical Society, Perkin Transactions 1 . 2002,第5期

机译：环丙烷的开环反应。第7部分。2，2-二甲氧基环丙烷甲酸乙酯的硒化和氰基硒化
3. Oxidative scission of ethyl 2,2-dimethoxycyclopropanecarboxylates with lead tetraacetate. Synthesis of the unusual anhydride bis-acetals [J] . Graziano ML., Piccialli V. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第48期

机译：2,2-二甲氧基环丙烷甲酸乙酯与四乙酸铅的氧化分解。异常酸酐双缩醛的合成
4. Ring-opening reactions of ethyl-and vinyloxirane on HZSM-5 and CuZSM-5 catalysts [C] . A. Fasi, I. Palinko, I. Kiricasi International congress on catalysis;ICC . 2000

机译：乙基环氧乙烷和乙烯基环氧乙烷在HZSM-5和CuZSM-5催化剂上的开环反应
5. Chemistry of 1,1,2,2,9,9,10,10-octafluoro-[2,2]-paracyclophane: Its synthesis and reactions. [D] . Duan, Jian-Xin. 2001

机译：1,1,2,2,9,9,10,10-八氟-[2,2]-对环环烷的化学反应：其合成和反应。
6. Diastereoselective Synthesis of 2-Phenylselenenyl-13-anti-Diols and 2-Phenylselenenyl-13-anti-Azido-Alcohols via Hydroxy- and Azido-Selenenylation Reactions [O] . Serena Riela, Carmela Aprile, Michelangelo Gruttadauria, 2005

机译：通过羟基和叠氮亚硒基化反应的非对映选择性合成2-苯基硒烯-13-反二醇和2-苯基硒烯-13-反叠氮基醇
7. On the Ring-opening Reactions of the Furan Compounds. III. On the Condensation of Furfural with Methyl Ethyl Ketone by Alkali [O] . Hiroshi Midorikawa 1953

机译：在呋喃化合物的开环反应上。 III。用碱用碱用甲基乙基酮的凝结凝结在糠醛上
8. Permeation of bis(2-fluoro-2,2-dinitroethyl) formal (FEFO), ethyl 4,4-dinitropentanoate (EDNP), ethyl 4-nitropentanoate (ENP), and 1,2,4-trichlorobenzene (TCB) through barrier membranes [R] . Shepodd, T. J. , Daniel, A. R. , Buffleben, G. M. , 1994

机译：双（2-氟-2,2-二硝基乙基）缩甲醛（FEFO），4,4-二硝基戊酸乙酯（EDNp），4-硝基戊酸乙酯（ENp）和1,2,4-三氯苯（TCB）通过屏障的渗透膜

Ring-opening reactions of cyclopropanes. Part 7. Selenenylation and cyanoselenenylation of ethyl 2,2-dimethoxycyclopropanecarboxylates

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