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Surface treatment optimization of pigmentary TiO_2 from an industrial aspect

机译:从工业角度优化颜料型TiO_2的表面处理

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Industrial processes are most often limited in the means of production conditions, e.g., chemical agents' selection and consumption, and time and energy conditions. In the present work, we succeeded in synthesizing a homogeneous silica layer on titanium dioxide (TiO_2) core using moderate time and temperature conditions. The structure of the surface coated pigmentary TiO_2 was characterized by scanning electron microscopy, transmission electron microscopy, and EDS. In our research isoelectric point (IEP) of TiO_2 was determined, which occurred when the solution pH was ~4. In the meantime, the precipitation of SiO_2 on TiO_2 surface resulted in the shift of IEP. In addition, Fourier transform infrared spectroscopy and Brunauer-Emmett-Teller analysis were applied in order to determine differences in surface microstructure. Coating parameters were optimized to attain desired morphology of precipitated Si-hydroxide, which in turn provides improvements in one or more important performance properties such as hiding power efficiency, which was determined by the means of UV-Vis light transmittance.
机译:工业过程通常在生产条件上受到限制,例如化学试剂的选择和消耗以及时间和能量条件。在目前的工作中,我们成功地在适当的时间和温度条件下在二氧化钛(TiO_2)核上合成了均匀的二氧化硅层。通过扫描电子显微镜,透射电子显微镜和EDS表征了表面涂覆的颜料TiO_2的结构。在我们的研究中,确定了TiO_2的等电点(IEP),该等电点发生在溶液的pH值约为4时。同时,SiO_2在TiO_2表面上的沉淀导致IEP的移动。此外,为了确定表面微观结构的差异,应用了傅里叶变换红外光谱和Brunauer-Emmett-Teller分析。优化涂层参数以获得所需的沉淀的氢氧化硅形态,这反过来又改善了一种或多种重要的性能,例如通过UV-Vis透光率确定的遮盖力效率。

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