Synthesis and radiation curing of acrylated castor oil glycerides

Rene Mueller; Guido Wilke

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Synthesis and radiation curing of acrylated castor oil glycerides

机译：丙烯酸蓖麻油甘油酯的合成及辐射固化

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摘要

Synthesis and UV-curing of acrylated castor oil glycerides are described. Transesterification of castor oil with specific amounts of glycerol followed by conversion to castor oil acrylate esters lead to UV-curable binders with variable functionality per mass. The used raw materials are renewable, so that 100% bio-based resins can be obtained with this method. A possible purpose for these reactive binders is to balance the mechanical properties of hard radiation curable coatings.

机译：描述了丙烯酸化的蓖麻油甘油酯的合成和UV固化。蓖麻油与特定量的甘油进行酯交换，然后转化为蓖麻油丙烯酸酯，得到每单位质量官能度可变的可紫外光固化的粘合剂。使用的原材料是可再生的，因此可以通过这种方法获得100％的生物基树脂。这些反应性粘合剂的可能目的是平衡可辐射固化的硬涂层的机械性能。

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来源
《JCT research》 |2014年第6期|873-882|共10页
作者
Rene Mueller; Guido Wilke;
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作者单位

University of Applied Sciences Esslingen, Esslingen, Germany;

University of Applied Sciences Esslingen, Esslingen, Germany;

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原文格式 PDF
正文语种 eng
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关键词
100 bio-based; Glycerol-modified acrylic castor oil; Radiation curing; Method for targeted functionality;

机译：100％基于生物甘油改性的丙烯酸蓖麻油;辐射固化;目标功能的方法;

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专利

1. Curing Copolymerization Kinetics of Styrene with Maleated Castor Oil Glycerides Obtained from Biodiesel-Derived Crude Glycerol [J] . Echeverri David A., Jaramillo Franklin, Rios Luis A. Journal of Applied Polymer Science . 2015,第3a4期

机译：从生物柴油衍生的甘油制得的苯乙烯与马来酸蓖麻油甘油酯的固化共聚动力学
2. Synthesis and properties of radiation modified thermally cured castor oil based polyurethanes [J] . Aba Mortley, H.W. Bonin, V.T. Bui Nuclear Instruments & Methods in Physics Research. B, Beam Interactions with Materials and Atoms . 2007,第1期

机译：辐射改性的蓖麻油基热固化聚氨酯的合成与性能
3. CASTOR OIL-BASED POLYURETHANES .1. STRUCTURAL CHARACTERIZATION OF CASTOR OIL - NATURE OF INTACT GLYCERIDES AND DISTRIBUTION OF HYDROXYL GROUPS [J] . Tran NB., Pham QT., Vialle J. Polymer: The International Journal for the Science and Technology of Polymers . 1997,第10期

机译：蓖麻油基聚氨酯1。蓖麻油的结构特征-完整甘油的性质和羟基的分布。
4. Synthesis of Polyfunctional Castor Oil-based Polyurethane Acrylate by the Auxiliary of Thiol-ene Click Reaction [C] . GUAN Xiaoyuan, CHEN Guangxue, HE Minghui China Academic Conference on Printing and Packaging . 2015

机译：通过硫醇-NEE键点击反应的助剂合成多功能蓖麻油基聚氨酯丙烯酸酯
5. Evaluation of castor acrylated monomer in acrylic latexes for one-component, low VOC, low odor, ambient cure, architectural coatings [D] . King, Corey Lee. 2000

机译：单组分，低VOC，低气味，环境固化，建筑涂料的丙烯酸胶乳中蓖麻酸酯丙烯酸酯单体的评估
6. Synthesis and Properties of Moisture-Cured Reactive Polyurethane Containing Castor Oil and Oxime Compounds [O] . Zheng-Ying Wu 2020

机译：含有蓖麻油和肟化合物的水分固化反应性聚氨酯的合成与性能
7. Synthesis and performance of a thermosetting resin: Acrylated epoxidized soybean oil curing with a rosin-based acrylamide [O] . Yanping Yang, Minggui Shen, Xin Huang, 2016

机译：热固性树脂的合成与性能：用松香基丙烯酰胺丙烯酸酯化环氧化大豆油固化
8. Exposure Assessment of Acrylates/Methacrylates in Radiation-Cured Applications [R] . 1987

机译：辐射固化应用中丙烯酸酯/甲基丙烯酸酯的暴露评估

Synthesis and radiation curing of acrylated castor oil glycerides

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