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Facile creation of superhydrophobic surface with fluorine-silicon polymer under ambient atmosphere

机译:在环境气氛下用氟硅聚合物轻松形成超疏水表面

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摘要

A fluorine-silicon polymer of poly(styrene-co-1H,1H,2H,2H-perfluorooctyl methacrylate-co-vi-nyltriethoxysilane) (PSFV) was synthesized by bulk polymerization, and superhydrophobic surfaces were subsequently fabricated utilizing phase separation technique in one step by casting PSFV copolymer solution under ambient atmosphere. The PSFV copolymer was dissolved in tetrahydrofuran (THF), and then ethanol was added into the solution to induce phase separation. The surface morphologies of the copolymer films were controlled by the degree of phase separation, which could be tuned easily by the ethanol/THF volume ratio and the solution's initial concentration. Scanning electron microscopy observations indicated that the superhydrophobic copolymer film had a rough surface with a binary hierarchical structure. A brief explanation of the formation of the special microstruc-ture was put forward. The water contact angle and sliding angle of the superhydrophobic PSFV surface were measured as 162° and 4°, respectively. The simplicity of the operation's process might make the superhydrophobic surface potentially useful in a variety of applications.
机译:通过本体聚合法合成了聚(苯乙烯-co-1H,1H,2H,2H-甲基丙烯酸全氟辛基酯-共乙烯基三乙氧基硅烷)(PSFV)的氟硅聚合物,随后利用相分离技术在其中制备了超疏水表面步骤是在环境气氛下浇铸PSFV共聚物溶液。将PSFV共聚物溶解在四氢呋喃(THF)中,然后将乙醇添加到溶液中以诱导相分离。共聚物薄膜的表面形貌受相分离程度的控制,而相分离程度可通过乙醇/ THF体积比和溶液的初始浓度轻松调节。扫描电子显微镜观察表明,超疏水共聚物膜具有粗糙的表面,具有二元分层结构。提出了对特殊微结构形成的简要解释。超疏水性PSFV表面的水接触角和滑动角分别测量为162°和4°。操作过程的简单性可能会使超疏水表面在各种应用中潜在有用。

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