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Anti-fingerprints fluorinated coating for anodized titanium avoiding color alteration

机译:防指纹的氟化涂层,用于阳极氧化钛,避免颜色改变

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摘要

In this study amorphous fluorinated coatings applied to anodized titanium surface have been investigated. A copolymer between tetrafluoro-ethylene and perfiuoro-4-trifluoromethoxy-l,3-dioxole (AD60) and two perfluoropolyether containing ammonium phosphate (F10) or triethoxysilane (S10) functionalities have been tested. To estimate the color alteration of the anodized titanium surfaces due to the application of the coatings, spectrophotometric analyses have been made. Water and n-dodecane contact angles as well as apparent surface energy have been evaluated. Ellipsometry and atomic force microscopy data have been used to measure the thickness of the fluorinated coatings. A tailored mechanical preliminary test has also been explored to evaluate the adhesion of the coatings on the anodized titanium surface. The resistance to surface soiling with castor oil was also preliminarily investigated. The fluorinated coating tested on anodized titanium showed a low apparent surface energy and high chromatic aspect conservation, this is particularly evident for the titanium anodized coated with triethoxysilane functionalities fluoropolymers S10.
机译:在这项研究中,已经研究了应用于阳极氧化钛表面的无定形氟化涂层。测试了四氟乙烯与全氟-4-三氟甲氧基-1,3-二恶唑(AD60)和两种含磷酸铵(F10)或三乙氧基硅烷(S10)官能团的全氟聚醚之间的共聚物。为了估计由于涂层的应用而导致的阳极氧化钛表面的颜色变化,已经进行了分光光度分析。已经评估了水和正十二烷的接触角以及表观表面能。椭偏和原子力显微镜数据已用于测量氟化涂层的厚度。还研究了量身定制的机械初步测试,以评估涂层在阳极氧化钛表面上的附着力。还初步研究了蓖麻油对表面污染的抵抗力。在阳极氧化的钛上测试的氟化涂层显示出较低的表观表面能和较高的彩色外观守恒,这对于用三乙氧基硅烷官能团的含氟聚合物S10阳极氧化的钛尤为明显。

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  • 来源
    《JCT research》 |2011年第2期|p.153-160|共8页
  • 作者单位

    Dipartimento di Chimica, Materiali e Ingegneria Chimica G. Natta, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy;

    Praxair S.r.l., 23804 Monte Marenzo, LC, Italy;

    Dipartimento di Chimica, Materiali e Ingegneria Chimica G. Natta, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy;

    Dipartimento di Chimica, Materiali e Ingegneria Chimica G. Natta, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy;

    Dipartimento di Chimica, Materiali e Ingegneria Chimica G. Natta, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy;

    Dipartimento di Chimica, Materiali e Ingegneria Chimica G. Natta, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy;

    Dipartimento di Chimica, Materiali e Ingegneria Chimica G. Natta, Politecnico di Milano, via Mancinelli 7, 20131 Milan, Italy;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    anodized titanium; fluorinated coatings; color alteration; anti-fingerprint;

    机译:阳极钛氟化涂料;颜色变化;防指纹;

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