Design and synthesis of metal ion-recognition-induced conjugated polymers: An approach to metal ion sensory materials

Bing Wang; Michael R.Wasielewski

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Design and synthesis of metal ion-recognition-induced conjugated polymers: An approach to metal ion sensory materials

机译：金属离子识别诱导的共轭聚合物的设计与合成：金属离子感官材料的一种方法

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The synthesis and metal ion responsive properties of two 2, 2'-bipyridyl-phenylene-vinylene-based polymers is reported. These polymers are designed to be partially conjugated in their metal-free state and fully conjugated when exposed to metal ions so that the ion-induced conjugation enhancement can be transduced into a measurable signal. It is found that these polymers exhibit highly ionochromic effects with a wide variety of transition and main group metal ions excluding metal ions of the alkali and alkaline earth groups.

机译：报道了两种基于2，2'-联吡啶基-亚苯基-亚乙烯基的聚合物的合成和金属离子响应性能。这些聚合物被设计为在其无金属状态下部分共轭，并在暴露于金属离子时完全共轭，因此离子诱导的共轭增强作用可转换为可测量的信号。发现这些聚合物表现出高度的电致变色效应，除了碱金属和碱土金属基团的金属离子外，还具有多种过渡金属和主族金属离子。

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《Journal of the American Chemical Society》 |1997年第1期|p.12-21|共10页
作者
Bing Wang; Michael R.Wasielewski;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
中图分类化学;
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机译：共轭聚合物和过渡金属氧化物的杂化材料：合成，表征和电致变色

Design and synthesis of metal ion-recognition-induced conjugated polymers: An approach to metal ion sensory materials

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