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首页> 外文期刊>Journal of Applied Physics >Electrical properties of A/B-site substituted Ni-deficient La(Ni_(0.6)Fe_(0.3))O_3 perovskites with A=Ag~+, Pb~(2+), Nd~(3+) and B=Mn~(3+), Ga~(3+)
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Electrical properties of A/B-site substituted Ni-deficient La(Ni_(0.6)Fe_(0.3))O_3 perovskites with A=Ag~+, Pb~(2+), Nd~(3+) and B=Mn~(3+), Ga~(3+)

机译:A / B-位取代Ni不足的La(Ni_(0.6)Fe_(0.3))O_3钙钛矿的电性能,其中A = Ag〜+,Pb〜(2 +),Nd〜(3+)和B = Mn〜 (3 +),Ga〜(3+)

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摘要

We report the structural and electron transport properties of a series of compounds where A/B-site substituted Ni-deficient La(Ni_(0.6)Fe_(0.3))O_3 compounds with A=Ag~+, Pb~(2+), Nd~(3+) and B=Mn~(3+), Ga~(3+) have been synthesized by a chemical route. Electrical resistivity was used as an indicator to explore the response of La(Ni_(0.6)Fe_(0.3))O_3 for different A/B-site substitutions. The rationalized explanation for the variations of resistivity with substitutions was based on the change in bond length and modification of band structure due to substitutional disorder. A variable range hopping conduction approach is employed to explain the temperature variation of resistivity, and the result suggest that disorder-induced localization of charge carriers dominates the electrical transport in these compounds.
机译:我们报告了一系列化合物的结构和电子传输性质,其中A / B位取代了A = Ag〜+,Pb〜(2 +),Ni缺乏的La(Ni_(0.6)Fe_(0.3))O_3化合物, Nd〜(3+)和B = Mn〜(3 +),Ga〜(3+)是通过化学方法合成的。电阻率作为指标,探讨了La(Ni_(0.6)Fe_(0.3))O_3对不同A / B位取代的响应。电阻率随置换而变化的合理解释是基于键长的变化和由于置换无序引起的能带结构的改变。使用可变范围跳跃传导方法来解释电阻率的温度变化,结果表明,由无序引起的电荷载流子局部化主导了这些化合物中的电传输。

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