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首页> 外文期刊>Journal of Central South University of Technology >Preparation of ultrafine α-Al_2O_3 powders by catalytic sintering of ammonium aluminum carbonate hydroxide at low temperature
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Preparation of ultrafine α-Al_2O_3 powders by catalytic sintering of ammonium aluminum carbonate hydroxide at low temperature

机译:氢氧化铝碳酸铝的低温催化烧结制备超细α-Al_2O_3粉体

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摘要

The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate (Al_2(SO_4)_3) and ammonium carbonate ((NH_4 )_2CO_3). The effects of α-Al_2O_3 seeds and mixture composed of α-Al_2O_3 and ammonium nitrate, as well as multiplex catalysts (AT) on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al_2O_3 seeds and the mixture of α-Al_2O_3 and ammonium nitrate can lower the phase transformation temperature of α-Al_2O_3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al_2O_3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly.
机译:利用硫酸铝(Al_2(SO_4)_3)和碳酸铵((NH_4)_2CO_3)合成了碳酸氢铝铵。分别研究了α-Al_2O_3晶种以及由α-Al_2O_3与硝酸铵组成的混合物以及多元催化剂(AT)对烧结过程中氧化铝的相变的影响。结果表明,α-Al_2O_3晶种以及α-Al_2O_3和硝酸铵的混合物可以在不同程度上降低α-Al_2O_3的相变温度,而获得的颗粒大量团聚。 AT对氧化铝的相变具有巨大的潜在协同作用,降低了α-Al_2O_3的相变温度,降低了颗粒间颈缩的趋势。因此,粉末颗粒的分散性显着改善。

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