Guest Controlled Packing in Inclusion Compounds

Gaëlle Ramon; Luigi R. Nassimbeni; Jana H. Taljaard

首页> 外文期刊>Journal of Chemical Crystallography >Guest Controlled Packing in Inclusion Compounds

【24h】

Guest Controlled Packing in Inclusion Compounds

机译：内含物的客人控制包装

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The structures of 9-(2,4,6-trimethylphenyl)-9H-xanthen-9-ol (the host, H) and its inclusion compounds with benzene (BZ), bromobenzene (BrBZ) and dimethyl sulfoxide (DMSO) were elucidated. The packing interactions correlated with results of their thermal stabilities, kinetics of desorption and rate of guest exchange. The kinetics of desorption of H·DMSO resulted in an activation energy of 35(1) kJ mol−1. A guest exchange experiment was carried out whereby H·DMSO converted to H·1.5BZ.

机译：阐明了9-（2,4,6-三甲基苯基）-9H-黄原9-ol（主体H）的结构及其与苯（BZ），溴苯（BrBZ）和二甲基亚砜（DMSO）的包合化合物。堆积相互作用与其热稳定性，解吸动力学和客体交换速率的结果相关。 H·DMSO的解吸动力学导致活化能为35（1）kJ mol-1 。进行客体交换实验，由此将H·DMSO转化为H·1.5BZ。

著录项

来源
《Journal of Chemical Crystallography》 |2012年第10期|p.1014-1021|共8页
作者
Gaëlle Ramon; Luigi R. Nassimbeni; Jana H. Taljaard;
展开▼
作者单位

Department of Chemistry, University of Cape Town, P.D. Hahn Building, Rondebosch, 7701, South Africa;

Department of Chemistry, University of Cape Town, P.D. Hahn Building, Rondebosch, 7701, South Africa;

Sasol Technologies R&ampD, Klasie Havenga Road 1, Sasolburg, 1947, South Africa;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Crystal engineering; Inclusion compounds; Crystal structure; Kinetics;

机译：晶体工程夹杂物晶体结构运动学;

相似文献

外文文献
中文文献
专利

1. Guest controlled packing in inclusion compounds [J] . Ramon G., Nassimbeni L.R., Taljaard J.H. Journal of chemical crystallography . 2012,第10期

机译：客体控制内含物的填充
2. Controlling the Packing of Metal-Organic Layers by Inclusion of Polymer Guests [J] . Le Ouay Benjamin, Takaya Hikaru, Uemura Takashi Journal of the American Chemical Society . 2019,第37期

机译：通过包含聚合物来宾控制金属有机层的堆积
3. Inclusion compounds with mixed guests: controlled stoichiometries and kinetics of enclathration [J] . Leonard J. Barbour Mino R. Caira Tanya le Roex and Luigi R. Nassimbeni Journal of the Chemical Society, Perkin Transactions 2 . 2002,第12期

机译：混合客体的夹杂物：可控的化学计量比和包合动力学
4. ~(13)C-NMR Observed Conformations and Motions of Neat Liquid and Crystalline M-Hexatriacontane and as a Guest in the Narrow Channels of Its Inclusion Compound Formed with α-Cyclodextrin [C] . M. A. Hunt, S. Villar-Rodil, M. A. Gomez-Fatou, Symposium on lNMR spectroscopy of polymers: Innovative strategies for complex macromolecules . 2011

机译：〜（13）C-NMR观察整个液体和结晶M-六六六乙烷的构象和运动，以及用α-环糊精形成的狭窄通道中的窄通道中的客体
5. Removing centrosymmetric packing using host -guest inclusion [D] . Rashid, Ali N. 2001

机译：使用宿主-客体包含移除中心对称包装
6. Solid γ-Cyclodextrin Inclusion Compound with Gingerols a Multi-Component Guest: Preparation Properties and Application in Yogurt [O] . Joana M. Pais, Bruna Pereira, Filipe A. Almeida Paz, 2020

机译：带有多种成分的姜油的固态γ-环糊精包合物：制备性质及在酸奶中的应用
7. Complex packing motifs templated by a pseudo-spherical guest: The structure of \u3b2-cyclodextrin / adamantane inclusion compounds [O] . Enright, Gary D., Udachin, Konstantin A., Ripmeester, John A. 2010

机译：拟球形客体为模板的复杂包装图案：\ u3b2-环糊精/金刚烷包合物的结构

Guest Controlled Packing in Inclusion Compounds

摘要

著录项

相似文献

相关主题

期刊订阅