Syntheses, Characterizations and Crystal Structures of Two Copper Coordination Polymers Both Having Cu2Cl2 Bridging Subunit [CuI(bipy)1/2Cl]n(1) and {[(CuII)4(phen)4(SSA)2Cl2](H2O)2(DMF)2}n(2)

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Syntheses, Characterizations and Crystal Structures of Two Copper Coordination Polymers Both Having Cu₂Cl₂ Bridging Subunit [CuI(bipy)_1/2Cl]_n(1) and {[(CuII)₄(phen)₄(SSA)₂Cl₂](H₂O)₂(DMF)₂}_n(2)

机译：两种具有Cu _{2 Cl _{2 桥联亚基[Cu I （bipy）_{1的铜配位聚合物的合成，表征和晶体结构/ 2 Cl] _{n （1）和{[（（Cu II ）_{4 （phen）_{4 （SSA）_{2 Cl _{2 ]（H _{2 O）_{2 （DMF）_{2 } _{n （2）}}}}}}}}}}}}

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Abstract Two copper coordination polymers [CuI(bipy)_1/2Cl]_n(1) and {[(CuII)₄(phen)₄(SSA)₂Cl₂] (H₂O)₂(DMF)₂}_n(2)(bipy = 4,4′-bipyridine, phen = 1,10-phenanthroline, H₃SSA = 5-sulfosalicylic acid, DMF = N,N-dimethylformamide) have been prepared and characterized by X-ray diffraction, elemental analysis, IR spectrum and 2 was also studied by cyclic voltammetric method. X-ray analysis indicates that both of them have Cu₂Cl₂ bridging subunit. Complex 1 is a two dimensional network structure. While 2 shows a one dimensional zigzag chain. Electrochemistry studies reveal that complex 2 undergo a quasi reversible one-electron metal-centered redox process at E _1/2 = +0.062 V.

机译：摘要两种铜配位聚合物[Cu I （bipy）_{1/2 Cl] _{n （1）和{[（（Cu II ）_{4 （phen）_{4 （SSA）_{2 Cl _{2 ]（H _{2 O）_{2 （DMF）_{2 } _{n （2）（bipy = 4,4'-联吡啶，phen =制备了1,10-菲咯啉，H _{3 SSA = 5-磺基水杨酸，DMF = N，N-二甲基甲酰胺），并通过X射线衍射，元素分析，IR光谱和2通过循环伏安法研究。 X射线分析表明它们都具有Cu _{2 Cl _{2 桥连亚基。复合体1是二维网络结构。而2显示一维锯齿形链。电化学研究表明，配合物2在E _{1/2 = +0.062 V时经历了准可逆的单电子金属中心氧化还原过程。}}}}}}}}}}}}}}

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《Journal of Chemical Crystallography》 |2011年第1期|p.34-38|共5页
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Syntheses, Characterizations and Crystal Structures of Two Copper Coordination Polymers Both Having Cu2Cl2 Bridging Subunit [CuI(bipy)1/2Cl]n(1) and {[(CuII)4(phen)4(SSA)2Cl2](H2O)2(DMF)2}n(2)

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Syntheses, Characterizations and Crystal Structures of Two Copper Coordination Polymers Both Having Cu₂Cl₂ Bridging Subunit [CuI(bipy)_1/2Cl]_n(1) and {[(CuII)₄(phen)₄(SSA)₂Cl₂](H₂O)₂(DMF)₂}_n(2)