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Atmospheric Benzo[a]pyrene and vanadium evidence for the presence of petroleum coke dust in the Athabasca Oil Sands Region, Alberta, Canada

机译:大气中苯并[a] van和钒的证据表明,加拿大艾伯塔省阿萨巴斯卡油砂地区存在石油焦炭粉尘

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摘要

Oil mining activities may link to the air quality in Athabasca Oil Sands Region (AOSR) in Alberta, Canada. Polycyclic aromatic hydrocarbons (PAHs), alkylated PAHs, dibenzothiophenes (DBTs), and trace metals in aerosol samples at three near source sites (AMS11, AMS05 and AMS13) in the Fort MacKay and Fort McMurray area during January 2011 to December 2014, were collected and analyzed. Concentrations of total PAHs, total alkylated PAHs, DBTs decreased as the distance from the geographical reference point increased. Average concentrations of Benzo[a]pyrene (B(a)P) and Vanadium (V) were from 0.42 to 0.68 ng m(-3), and from 1.14 to 136 ng m(-3) respectively at AMS11, from 0.10 to 0.14 ng m(-3), and from 0.79 to 1.45 ng m(-3) respectively at AMS05, and from 0.03 to 0.06 ng m(-3), and from 0.56 to 0.80 ng m(-3) respectively at AMS13 during 2011-2014. High V, B(a)P, total PAHs, total alkylated-PAHs, DBTs and Alkylated DBTs were observed in AMS11, especially in the south and south-eastern wind direction, suggesting that V and polycyclic aromatic compounds (PACs) could come from the same pollution source. High positive correlation between V and B(a)P only appeared at the AMS11 site, especially in the prevailing wind sector. Together with the principal component analysis (PCA) results and Fluoranthene/(Fluoranthene Pyrene) ratio, all further confirmed the common petrogenic source, that was petroleum coke dust, contributing to atmospheric PAHs and metals. (C) 2017 Elsevier Ltd. All rights reserved.
机译:石油开采活动可能与加拿大艾伯塔省阿萨巴斯卡油砂地区(AOSR)的空气质量有关。收集了2011年1月至2014年12月期间在Fort MacKay和Fort McMurray地区的三个近源站点(AMS11,AMS05和AMS13)的气溶胶样品中的多环芳烃(PAH),烷基化PAH,二苯并噻吩(DBT)和微量金属并进行分析。随着距地理参考点的距离增加,总PAH,烷基化PAH,DBT的浓度降低。在AMS11中,苯并[a] py(B(a)P)和钒(V)的平均浓度分别为0.42至0.68 ng m(-3)和1.14至136 ng m(-3),从0.10至在AMS05期间,分别为0.14 ng m(-3)和0.79至1.45 ng m(-3),在AMS13期间分别为0.03至0.06 ng m(-3)和0.56至0.80 ng m(-3) 2011-2014。在AMS11中观察到较高的V,B(a)P,总PAH,总烷基化PAH,DBT和烷基化DBT,尤其是在南风向和东南风向,这表明V和多环芳族化合物(PAC)可能来自相同的污染源V和B(a)P之间的高度正相关仅出现在AMS11站点上,尤其是在风电领域。再加上主成分分析(PCA)结果和荧蒽/(荧蒽)比,都进一步确认了常见的成岩来源,即石油焦炭粉尘,对大气中的PAH和金属有贡献。 (C)2017 Elsevier Ltd.保留所有权利。

著录项

  • 来源
    《Journal of Cleaner Production》 |2018年第1期|592-599|共8页
  • 作者

    Xu Guojie;

  • 作者单位

    Nanjing Univ Informat Sci & Technol, Collaborat Innovat Ctr Forecast & Evaluat Meteoro, Key Lab Aerosol Cloud Precipitat, China Meteorol Adm, Nanjing 210044, Jiangsu, Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Aerosol; Benzoapyrene; Metals; Petroleum coke; Oil sands;

    机译:气雾剂;苯并[a] py;金属;石油焦;油砂;

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