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首页> 外文期刊>Journal of Cleaner Production >Innovative application of biopolymer composite as proton exchange membrane in microbial fuel cell utilizing real wastewater for electricity generation
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Innovative application of biopolymer composite as proton exchange membrane in microbial fuel cell utilizing real wastewater for electricity generation

机译:生物聚合物复合材料的创新应用在微生物燃料电池中利用实际废水中的微生物燃料电池

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摘要

Biopolymer composite for application as proton exchange membrane in microbial fuel cell (MFC) is investigated. Different amounts of PHB ranging from 5 to 15% (w/w) are composited within medium -chain-length polyhydroxyalkanoates (mcl-PHA) matrix to produce a scl/mcl-PHA membrane. The composite is compared to Nafion membrane for improved directional proton conduction in MFC. Composites with 10 and 15% (w/w) of PHB records two-fold maximum voltage potential compared to Nafion. A power density of 601 mW/m(2) is recorded for PHB15% membrane, which is higher than that of Nafion (520 mW/ m(2)). The MFC setup with composite membrane also shows higher maximum voltage potential, water uptake, power and current densities, chemical oxygen demand (COD) removal, ammoniacal nitrogen (NH3-N) removal as well as coulombic efficiency (CE) recovery. Composite membrane exhibits stronger resistivity to oxygen diffusion from cathode compartment to anode chamber, subsequently improving the overall MFC performance with real wastewater as substrate. (C) 2020 Elsevier Ltd. All rights reserved.
机译:研究了用于微生物燃料电池(MFC)中的质子交换膜的基础聚合物复合材料。范围为5-15%(w / w)的不同量在中间支链多羟基烷烷(Mcl-PHA)基质中,以产生SCL / MCL-PHA膜。将复合材料与Nafion膜进行比较,以改善MFC中的定向质子传导。与Nafion相比,具有10和15%(W / W)的复合材料记录了两倍的最大电压电位。为PHB15%膜记录601mW / m(2)的功率密度,其高于Nafion(520mW / m(2))。具有复合膜的MFC设置还显示出更高的最大电压电位,水吸收,功率和电流密度,化学需氧量(COD)去除,氨氮(NH3-N)除去以及库仑效率(CE)回收。复合膜对从阴极室到阳极室的氧气扩散的电阻率更强,随后用实际废水作为基板改善整体MFC性能。 (c)2020 elestvier有限公司保留所有权利。

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