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Highly rigid, fire-resistant, and sustainable polybutylene adipate terephthalate/polybutylene succinate composites reinforced with surface-treated coffee husks

机译:高度刚性,耐火和可持续的聚丁烯己二酸酯/聚丁烯琥珀酸酯复合材料加强了表面处理过的咖啡壳

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摘要

Despite the increasing demand for eco-friendly polymer materials that can be employed in advanced industrial applications, the development of biodegradable polymer composites with advantageous mechanical properties and fire resistance remains a challenge. In this work, we fabricated fully biodegradable polybutylene adipate terephthalate (PBAT)/polybutylene succinate (PBS) composites reinforced with surface-treated coffee husks (CHs) with high rigidity, mechanical strength, and fire resistance. CH characterization confirmed that the surface was successfully treated with different C4 dicarboxylic acids. Morphological analysis of the composites revealed that the surface-treated CHs helped to improve both the compatibility between the matrices and the interfacial interaction between the filler and the matrices. The tensile strength and modulus of the composites increased by 96% and 278% compared to neat PBAT. Flammability and combustion tests confirmed that the combined effect of phosphorus and dicarboxylic acid surface treatment improved the fire-resistant behavior of the composites. This study thus presents a promising technique for the development of PBAT composites with suitable mechanical properties and fire resistance.
机译:尽管对可在先进的工业应用中使用的环保聚合物材料的需求不断增加,但可生物降解的聚合物复合材料的开发具有有利的机械性能和耐火性仍然是一个挑战。在这项工作中,我们制造了完全可生物降解的聚丁烯己二酸酯(PBAT)/聚丁烯琥珀酸酯(PBS)复合材料,用具有高刚性,机械强度和耐火性的表面处理过的咖啡壳(CHS)加强。 CH表征证实,用不同的C 4二羧酸成功处理表面。复合材料的形态学分析显示,表面处理的CHS有助于改善填料和基质之间的矩阵与界面相互作用之间的相容性。与整齐的PBAT相比,复合材料的拉伸强度和模量增加了96%和278%。易燃性和燃烧试验证实,磷和二羧酸表面处理的综合作用改善了复合材料的耐火性能。因此,该研究提出了具有合适机械性能和耐火性的PBAT复合材料的有希望的技术。

著录项

  • 来源
    《Journal of Cleaner Production》 |2021年第15期|128095.1-128095.9|共9页
  • 作者单位

    Chung Ang Univ Sch Chem Engn & Mat Sci Seoul 156756 South Korea;

    Chung Ang Univ Grad Sch Intelligence Energy & Ind Seoul 156756 South Korea;

    Chung Ang Univ Sch Chem Engn & Mat Sci Seoul 156756 South Korea|Chung Ang Univ Grad Sch Intelligence Energy & Ind Seoul 156756 South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Biocomposite; Lignocellulose; Fire resistance;

    机译:生物复合;木质纤维素;耐火性;

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