Studies on growth, spectral and mechanical properties of new organic NLO crystal: Guanidinium 4-nitrobenzoate (GuNB)

T. Arumanayagam; P. Murugakoothan

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Studies on growth, spectral and mechanical properties of new organic NLO crystal: Guanidinium 4-nitrobenzoate (GuNB)

机译：新型有机NLO晶体4-硝基苯甲酸胍（GuNB）的生长，光谱和力学性能的研究

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A new organic nonlinear optical single crystal guanidinium 4-nitrobenzoate (GuNB) was successfully grown by solution growth using the slow evaporation technique. Solubility and metastable zone width were determined for different solvents. The structure of the grown crystal has been determined by single crystal x-ray diffraction analysis. The presence of functional groups and coordination of para nitro benzoate ions in the GuNB crystal have been identified by FTIR and FT Raman spectroscopic studies. The optical transparency range has been studied through UV-vis-NIR spectroscopy. The second harmonic generation efficiency of the grown GuNB crystal has been obtained by the Kurtz-Perry powder technique. The laser induced surface damage threshold for the grown crystal has been measured using Nd: YAG laser. The mechanical behavior has also been studied by Vicker's microhardness test.

机译：通过使用缓慢蒸发技术进行溶液生长，成功地生长了一种新的有机非线性光学单晶4-硝基苯甲酸胍（GuNB）。确定了不同溶剂的溶解度和亚稳区域宽度。通过单晶X射线衍射分析确定了生长的晶体的结构。通过FTIR和FT拉曼光谱研究已经确定了GuNB晶体中官能团的存在和对硝基苯甲酸根离子的配位。通过紫外可见近红外光谱研究了光学透明范围。通过Kurtz-Perry粉末技术获得了生长的GuNB晶体的二次谐波产生效率。已使用Nd：YAG激光测量了生长晶体的激光诱导表面损伤阈值。机械性能也已经通过维氏显微硬度测试进行了研究。

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来源
《Journal of Crystal Growth》 |2013年第1期|304-307|共4页
作者
T. Arumanayagam; P. Murugakoothan;
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作者单位

PG and Research Department of Physics, Pachiyappa's College, Chennai 600 030, India;

PG and Research Department of Physics, Pachiyappa's College, Chennai 600 030, India;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
A1. Characterization; A1. Recrystallization; A2. Growth from solution; B2. Nonlinear optic materiA1s;

机译：A1。表征;A1。重结晶;A2。从解决方案中成长;B2。非线性光学材料;

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1. Growth, linear and nonlinear optical studies on guanidinium 4-nitrobenzoate (GuNB): An organic NLO material [J] . Arumanayagam T., Murugakoothan P. Optik: Zeitschrift fur Licht- und Elektronenoptik: = Journal for Light-and Electronoptic . 2012,第13期

机译：4-硝基苯甲酸胍（GuNB）的生长，线性和非线性光学研究：一种有机NLO材料
2. Studies on growth, spectral, optical and mechanical properties of new organic NLO crystal: Guanidinium l-glutamate (GuGL) [J] . Arumanayagam T., Ananth S., Murugakoothan P. Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2012,第Null期

机译：新型有机NLO晶体-谷氨酸胍（GuGL）的生长，光谱，光学和机械性能的研究
3. Electronic structure, vibrational spectral and intervening orbital interactions studies of NLO material: Guanidinium 4-nitrobenzoate [J] . Sasikala V., Sajan D., Sabu K. Job, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2015,第Null期

机译：NLO材料：4-硝基苯甲酸胍盐的电子结构，振动光谱和居间轨道相互作用的研究
4. Growth, Spectral and Thermal Studies of Organic NLO Crystals of DSAS by SNM Technique [C] . R. Gunaseelan, R. Jerald Vijay, G. Ramalingam, DAE Solid State Physics Symposium . 2011

机译：SNM技术的DSA有机NLO晶体的生长，光谱和热研究
5. Main-chain chiral smectic liquid crystalline polymers for electro-mechanical and NLO application. [D] . Yang, Hong. 2007

机译：用于机电和NLO应用的主链手性近晶液晶聚合物。
6. Growth, Mechanical, Thermal and Spectral Properties of Cr3+∶MgMoO4 Crystal [O] . Lingyun Li, Yisheng Huang, Lizhen Zhang, 2009

机译：Cr3 + ∶MgMoO4晶体的生长，力学，热学和光谱性质
7. A study on the properties Synthesis ,Growth, spectral, structural, optical thermal studies of a new organic crystal and NLO applications of N-(tert-butyl)-4-(nitrophenyl imidazo1,2-apyrazin-3-amine [O] . K.Elumalai Kuppan, K.Sakthiumurugesan . 2018

机译：N-（叔丁基）-4-（硝基苯基咪唑1,2-A吡嗪-3-胺的新有机晶体和NLO应用的性能合成，生长，光谱，结构，光学热研究的研究

Studies on growth, spectral and mechanical properties of new organic NLO crystal: Guanidinium 4-nitrobenzoate (GuNB)

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