Growth of (Perylene)_2 [Pd(mnt)_2] crystals

M.L Afonso; R.A.L Silva; M. Matos; E.B. Lopes; J.T. Coutinho; LC.J. Pereira; R.T. Henriques; M. Almeida

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Growth of (Perylene)_2 [Pd(mnt)_2] crystals

机译：（Perylene）_2 [Pd（mnt）_2]晶体的生长

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The conditions for the growth of (0Perylene)_2 [Pd(mnt)_2] crystals either by chemical oxidation and electrochemical routes are described. The electrocrystallisation is limited by close proximity of the oxidation potentials of the perylene donor and [Pd(mnt)_2]~ anion, and depending on the experimental conditions different morphologies can be obtained. (Per)_2 [Pd(mnt)_2] crystals obtained by elecrocrys-tallisation were found to be mainly of the β-polymorph with properties comparable to the Cu, Ni and Pt analogues previously described at variance with those obtained by chemical oxidation which are mainly of the α-polymorph .

机译：描述了通过化学氧化和电化学途径生长（0Perylene）_2 [Pd（mnt）_2]晶体的条件。电结晶受到the供体和[Pd（mnt）_2]〜阴离子的氧化电位的紧密接近性的限制，并且根据实验条件，可以获得不同的形态。发现通过电子爆裂法获得的（Per）_2 [Pd（mnt）_2]晶体主要是β-多晶型物，其性质可与前述的Cu，Ni和Pt类似物相媲美，与通过化学氧化获得的相类似。主要是α-多晶型物。

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来源
《Journal of Crystal Growth》 |2012年第1期|p.56-60|共5页
作者
M.L Afonso; R.A.L Silva; M. Matos; E.B. Lopes; J.T. Coutinho; LC.J. Pereira; R.T. Henriques; M. Almeida;
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作者单位

Departamento de Quimica, Instituto Tecnologico e Nuclear/CFMOJL, P-2686-953 Sacavem, Portugal;

Departamento de Quimica, Instituto Tecnologico e Nuclear/CFMOJL, P-2686-953 Sacavem, Portugal;

Departamento de Engenharia Quimica Instituto Superior de Engenharia de Lisboa, P-1900 Lisboa, Portugal,Institute de Telecomunicacoes, Polo de Lisboa, Av. Rovisco Pais, P-1049-001 Lisboa, Portugal;

Departamento de Quimica, Instituto Tecnologico e Nuclear/CFMOJL, P-2686-953 Sacavem, Portugal,Departamento de Engenharia Quimica Instituto Superior de Engenharia de Lisboa, P-1900 Lisboa, Portugal,Institute de Telecomunicacoes, Polo de Lisboa, Av. Rovisco Pais, P-1049-001 Lisboa, Portugal;

Departamento de Quimica, Instituto Tecnologico e Nuclear/CFMOJL, P-2686-953 Sacavem, Portugal;

Departamento de Quimica, Instituto Tecnologico e Nuclear/CFMOJL, P-2686-953 Sacavem, Portugal;

Institute de Telecomunicacoes, Polo de Lisboa, Av. Rovisco Pais, P-1049-001 Lisboa, Portugal;

Departamento de Quimica, Instituto Tecnologico e Nuclear/CFMOJL, P-2686-953 Sacavem, Portugal;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
A2. electrochemical growth; B1. aromatic compounds; B1. perylene salts; B1. palladium dithiolates; B2. molecular conductors;

机译：A2。电化学生长B1。芳香化合物B1。 ylene盐;B1。二硫代钯盐;B2。分子导体;

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机译：[Pd（mnt）_2]〜（2-）的不对称氧化产物：（Bu_4N）_2 [PD（mnt）{O_2S_2C_2（CN）_2}]和一维配位聚合物（Bu_4N）_2 [的合成和晶体结构AgPd（mnt）{O_2S_2C_2（CN）_2}] _ 2（mnt = 1,2-二氰基-1,2-亚乙基二硫醇盐
2. Unsymmetrical Oxygenation Products of [Pd(mmt)_2~(2-):Syntheses and Crystal Structures of (Bu_4N)_2[Pd(mnt){O_2S_2C_2(CN)_2}] and One-Dimensional Coordination Polymer (Bu_4N)_2[AgPd(mnt){O_2S_2C_2(CN)_2}]_2 (mnt=1,2-Dicyano-1,2-ethylenedithiolato) [J] . Kunihisa Sugimoto, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Bulletin of the Chemical Society of Japan . 2000,第2期

机译：[Pd（mmt）_2〜（2-）的不对称氧化产物：（Bu_4N）_2 [Pd（mnt）{O_2S_2C_2（CN）_2}]和一维配位聚合物（Bu_4N）_2 [AgPd]的合成和晶体结构（mnt）{O_2S_2C_2（CN）_2}} _ 2（mnt = 1,2-二氰基-1,2-亚乙基二硫代拉托）
3. Structural studies of [Pt(CNMe)(4)][M(mnt)(2)](n) {M = Pd or Pt, mnt = [S2C2(CN)(2)](2-), n = 1 or 2}: structure-dependent paramagnetism of three crystal forms of [Pt(CNMe)(4)][Pt(mnt)(2)](2) [J] . Bois H., Crossley JG., Guillorit JC., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第17期

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4. Electrochemical Quartz Crystal Microbalance Studies of the Growth of Perylene-Containing Films [C] . V. Cammarata, N. Hao, J. Metz, 219th National Meeting of the American Chemical Society, Mar 26-30, 2000, San Francisco, California . 2000

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机译：DR0248的纯化结晶和初步晶体学分析DR0248是一种来自放射性杜鹃球菌的MNT-HEPN融合蛋白。
7. Growth of (Perylene)(2) PD(MNT)(2) crystals [O] . Afonso M. L., Silva R. A. L., Matos M., 2012

机译：（Per）（2）PD（MNT）（2）晶体的生长

Growth of (Perylene)_2 [Pd(mnt)_2] crystals

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