Synthesis multifarious morphologies and sizes of YBO_3:Eu~(3+) phosphors, and clarification of the crystal structure of YBO_3

Xuan Guo; Yuhua Wang; Jiachi Zhang

首页> 外文期刊>Journal of Crystal Growth >Synthesis multifarious morphologies and sizes of YBO_3:Eu~(3+) phosphors, and clarification of the crystal structure of YBO_3

【24h】

Synthesis multifarious morphologies and sizes of YBO_3:Eu~(3+) phosphors, and clarification of the crystal structure of YBO_3

机译：YBO_3：Eu〜（3+）荧光粉的合成形貌和尺寸以及YBO_3晶体结构的澄清

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A series of multicrystal and monocrystal samples of yttrium orthoborate YBO_3:Eu with different morphologies and sizes were prepared by a simple hydrothermal (HT) method at a low temperature of 260 ℃ for 3 h, in the absence of any surfactant and template, without milling and post calcination. Samples are characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM). The morphologies and sizes of YBO_3:Eu, most of which are prepared for the first time, include polycrystalline nano-sheet; monocrystalline nano-sheet, nano-particle, submicro-sheet, submicro-rod and submicro-tube; micro-flower and micro-downy ball, which are assembled by orderly nano-sheets. At the same time, multifarious clear and high-quality selected-area electron diffraction (SAED) patterns including multicrystal diffraction rings and monocrystal diffraction spots were obtained for the first time, which provide abundant stuff to study the crystal structure of YBO_3. However, all the innermost diffraction rings or spots of SAED patterns cannot be indexed by the currently accepted hexagonal crystal structure of YBO_3, whose space group is P6_3/m and lattice parameters are a = 3.778 A, c = 8.810 A. On the other hand, the whole diffraction pattern can be successfully indexed by another hexagonal structure, whose space group is P6c2 and lattice parameters are a = 6.454 A, c=8.810 A. In addition, this structure is also supported by the XRD results. As a result, the crystal structure of YBO_3 is clarified.

机译：在没有任何表面活性剂和模板的情况下，在没有任何表面活性剂和模板的情况下，通过简单的水热法（HT）在260℃的低温下制备了一系列形态和大小不同的原硼酸钇YBO_3：Eu的多晶体和单晶样品，并进行了研磨。和煅烧后。样品通过X射线粉末衍射（XRD），透射电子显微镜（TEM），场发射扫描电子显微镜（FE-SEM）进行表征。 YBO_3：Eu的形貌和尺寸，大多数是首次制备，包括多晶纳米片。单晶纳米片，纳米颗粒，亚微片，亚微棒和亚微管；微花和微毛绒球，由有序的纳米片组装而成。同时，首次获得了包括多晶衍射环和单晶衍射斑在内的多种清晰，高质量的选区电子衍射图（SAED），为研究YBO_3的晶体结构提供了丰富的材料。但是，不能通过当前接受的YBO_3六方晶体结构（其空间群为P6_3 / m且晶格参数为a = 3.778 A，c = 8.810 A）来索引SAED图案的所有最里面的衍射环或斑点。，整个衍射图样可以成功地由另一个六边形结构索引，该六边形结构的空间组为P6c2，晶格参数为a = 6.454 A，c = 8.810A。此外，XRD结果也支持该结构。结果，阐明了YBO_3的晶体结构。

著录项

来源
《Journal of Crystal Growth》 |2009年第8期|2409-2417|共9页
作者
Xuan Guo; Yuhua Wang; Jiachi Zhang;
展开▼
作者单位

Department of Materials Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China;

Department of Materials Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China;

Department of Materials Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China;

展开▼
收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类
关键词
A1. Crystal morphology; A1. Crystal structure; A2. Hydrothermal crystal growth; B1. Rare-earth compounds; B1. Yttrium compounds; B2. Phosphors;

机译：A1。晶体形态A1。晶体结构A2。水热晶体生长;B1。稀土化合物;B1。钇化合物;B2。荧光粉;

相似文献

外文文献
中文文献
专利

1. COMBUSTION SYNTHESIS AND VUV PHOTOLUMINESCENCE STUDIES OF BORATE HOST PHOSPHORS YBO_3:RE~(3+) (RE = Eu~(3+), Tb~(3+)) FOR PDPs APPLICATIONS [J] . J. T. Ingle, R. P. Sonekar, S. K. Omanwar, Combustion Science and Technology . 2014,第1a3期

机译：硼酸根磷酸盐YBO_3：RE〜（3+）（RE = Eu〜（3+），Tb〜（3+））的燃烧合成和VUV光致发光研究
2. Effect of partially replacement of Gd~(3+) ions on fluorescence properties of YBO_3:Eu~(3+) phosphor synthesized via precipitation method [J] . K.A. Koparkar, N.S. Bajaj, S.K. Omanwar Optical Materials . 2015,第Jana期

机译：Gd〜（3+）离子部分置换对沉淀法合成YBO_3：Eu〜（3+）荧光粉荧光性质的影响
3. Effect of partially replacement of Gd~(3+) ions on fluorescence properties of YBO_3:Eu~(3+) phosphor synthesized via precipitation method [J] . K.A. Koparkar, N.S. Bajaj, S.K. Omanwar Optical Materials . 2015,第jana期

机译：Gd〜（3+）离子部分置换对沉淀法合成YBO_3：Eu〜（3+）荧光粉荧光性质的影响
4. A New Method for Preparation and Luminescence of YBO_3 :Eu~(3+) Phosphor [C] . Linyan Jia, Zhongbao Shao, Yanwen Tian International Conference on Advanced Engineering Materials and Technology . 2011

机译：YBO_3的制备和发光的一种新方法：EU〜（3+）磷光体
5. Applications of a three-body potential model and crystal field calculations to the simulation of europium(3+), erbium(3+) and ytterbium(3+) environments on lead silicate glass [D] . Peres, Tania 1999

机译：三体电势模型和晶体场计算在硅酸铅玻璃上（（3+），（3+）和（3+）环境模拟中的应用
6. The crystal structures of {LnCu5}3+ (Ln = Gd Dy and Ho) 15-metallacrown-5 complexes and a reevaluation of the isotypic EuIII analogue [O] . Anna Pavlishchuk, Dina Naumova, Matthias Zeller, 2019

机译：{LnCu5} 3+（Ln = GdDy和Ho）15-金属lacrown-5配合物的晶体结构和同型EuIII类似物的重新评估
7. Template synthesis, crystal structure and luminescent properties of neutral N4O3 tripodal LnIIIL complexes (Ln III = La3+, Eu3+, Gd3+, Tb 3+, Dy3+, Ho3+, Er3+, Tm3+ or Lu3+; H3L = Tris{3′-(2″- pyridyl)-5′-tert-butyl-2′-hydroxybenzylidene-2-iminoethyl}amine) [O] . Wong WK, Liang H, Guo J, 2004

机译：中性N4O3三脚架LnIIIL配合物（Ln III = La3 +，Eu3 +，Gd3 +，Tb 3 +，Dy3 +，Ho3 +，Er3 +，Tm3 +或Lu3 +的模板合成，晶体结构和发光特性; H3L = Tris {3'-（2''-吡啶基）-5'-叔丁基-2'-羟基亚苄基-2-亚氨基乙基}胺）

Synthesis multifarious morphologies and sizes of YBO_3:Eu~(3+) phosphors, and clarification of the crystal structure of YBO_3

摘要

著录项

相似文献

相关主题

期刊订阅