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首页> 外文期刊>Journal of Crystal Growth >Valence transition of Eu ions in GaN near the surface
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Valence transition of Eu ions in GaN near the surface

机译:表面附近GaN中Eu离子的价态跃迁

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摘要

The valence states of Eu ions doped in GaN were investigated by the core-level X-ray and resonant photoemission spectroscopy. Although the photoluminescence spectra show the emissions from only trivalent Eu ions, the existence of both divalent and trivalent Eu ions is suggested by the Eu 3d core-level spectra. Taking into account the results of the 4d--4f resonant photoemission measurements, it can be concluded that valence transition from Eu~3+ to Eu~2+ occurs near the surface of GaN.
机译:通过核能级X射线和共振光发射光谱研究了掺杂在GaN中的Eu离子的价态。尽管光致发光光谱仅显示来自三价Eu离子的发射,但Eu 3d核心能级光谱暗示了二价和三价Eu离子的存在。考虑到4d--4f共振光发射测量的结果,可以得出结论,在GaN表面附近发生了从Eu〜3 +到Eu〜2 +的价态跃迁。

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