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Leaching characteristics of copper flotation waste before and after vitrification

机译:玻璃化前后铜浮选废水的浸出特性

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Copper flotation waste from copper production using a pyrometallurgical process contains toxic metals such as Cu, Zn, Co and Pb. Because of the presence of trace amounts of these highly toxic metals, copper flotation waste contributes to environmental pollution. In this study, the leaching characteristics of copper flotation waste from the Black Sea Copper Works in Samsun, Turkey have been investigated before and after vitrification. Samples obtained from the factory were subjected to toxicity tests such as the extraction procedure toxicity test (EP Tox), the toxicity characteristic leaching procedure (TCLP) and the "method A" extraction procedure of the American Society of Testing and Materials. The leaching tests showed that the content of some elements in the waste before vitrification exceed the regulatory limits and cannot be disposed of in the present form. Therefore, a stabilization or inertization treatment is necessary prior to disposal. Vitrification was found to stabilize heavy metals in the copper flotation waste successfully and leaching of these metals was largely reduced. Therefore, vitrification can be an acceptable method for disposal of copper flotation waste. (c) 2006 Elsevier Ltd. All rights reserved.
机译:使用火法冶金生产铜所产生的铜浮选废料包含有毒金属,例如Cu,Zn,Co和Pb。由于存在痕量的这些高毒性金属,浮选废铜造成了环境污染。在这项研究中,研究了在玻璃化前后,土耳其萨姆森黑海铜厂的铜浮选废水的浸出特性。从工厂获得的样品经过毒性测试,例如提取程序毒性测试(EP Tox),毒性特征浸出程序(TCLP)和美国测试与材料学会的“方法A”提取程序。浸出试验表明,玻璃化之前废物中某些元素的含量超过了规定的限值,不能以当前形式进行处理。因此,在处置前必须进行稳定化或惰性化处理。发现玻璃化可以成功地稳定铜浮选废料中的重金属,并且大大减少了这些金属的浸出。因此,玻璃化可以作为处置铜浮选废料的可接受方法。 (c)2006 Elsevier Ltd.保留所有权利。

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