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首页> 外文期刊>Journal of environmental science and health >Residues of organochlorine pesticides and PCBs in some Brazilian municipal solid waste compost
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Residues of organochlorine pesticides and PCBs in some Brazilian municipal solid waste compost

机译:巴西某些城市固体废物堆肥中有机氯农药和多氯联苯的残留

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Persistent organic pollutants (POPs), organochlorine pesticides and polychlorinated biphenyls (PCBs), listed as per the Stockholm Convention (α-HCH, β-HCH, γ-HCH, p,p'-DDT, o, p'-DDT, p,p'-DDD, p,p'-DDE, aldrin, endrin, dieldrin, PCBs 28, 52, 118, 138,153, and 180), were analyzed in municipal solid waste (MSW) compost samples from three different Brazilian composting plants located in three Sao Paulo State cities: Araras, Araraquara and Sao Paulo (Vila Leopoldinha). Quantitative and qualitative analyses were carried out using gas chromatography electron capture detection (GC-ECD) and gas chromatography mass spectrometry (GC-MS) (Ion Trap, electron impact ionization), respectively. The samples were analyzed in triplicate and the target POPs were not detected by GC-ECD. Twelve pollutants were identified in two samples when qualitative analysis (GC-MS) was used (β-HCH, γ-HCH, p,p'-DDT, o,p'-DDT, p,p-DDD, and p,p'-DDE, PCBs 28, 118, 138, 153 and 180). The composting process has advantages such as urban solid waste reduction and landfill life-span increase, however the MSW compost quality, which can be utilized for agricultural purposes, should be evaluated and be controlled. This kind of study is the first step in making available information to answer questions regarding MSW compost for sustainable agricultural use, such as the pollutants accumulation in soil and in groundwater, and plants uptake.
机译:根据《斯德哥尔摩公约》列出的持久性有机污染物(POPs),有机氯农药和多氯联苯(PCB)(α-HCH,β-HCH,γ-HCH,p,p'-DDT,o,p'-DDT,p ,p'-DDD,p,p'-DDE,艾氏剂,异狄氏剂,狄氏剂,PCBs 28、52、118、138,153和180)在来自三个不同巴西堆肥厂的城市固体废物(MSW)堆肥样品中进行了分析在三个圣保罗州城市中:Araras,Araraquara和圣保罗(Vila Leopoldinha)。分别使用气相色谱电子捕获检测(GC-ECD)和气相色谱质谱(GC-MS)(离子阱,电子碰撞电离)进行定量和定性分析。样品进行了三次重复分析,GC-ECD未检测到目标POPs。当使用定性分析(GC-MS)时,在两个样品中鉴定出十二种污染物(β-HCH,γ-HCH,p,p'-DDT,o,p'-DDT,p,p-DDD和p,p -DDE,PCB 28、118、138、153和180)。堆肥过程具有减少城市固体废物和增加垃圾填埋场寿命等优点,但是应评估和控制可用于农业目的的城市固体废弃物堆肥质量。此类研究是提供信息以回答有关可持续农业使用的城市固体废弃物堆肥问题的第一步,例如土壤和地下水中污染物的积累以及植物的吸收。

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