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首页> 外文期刊>Journal of environmental science and health >Distribution of organophosphate insecticides in a Thai biomass-water system
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Distribution of organophosphate insecticides in a Thai biomass-water system

机译:泰国生物质-水系统中有机磷杀虫剂的分布

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Sorption and leaching of the organophosphate (OP) pesticides chlorpyrifos, profenofos, methyl parathion and malathion were investigated with four different types of biomass: coconut husk, rice husk, peat moss and peanut shell. Organic carbon contents of the biomass were in the range of 35.4-45.4%. Sorption studies were carried out by the batch (equilibrium) method at 4 different OP spike concentrations and at pH 3-7. Sorption isotherms conformed to a linear Freundlich equation and the Freundlich constant or sorption coefficient (K_D) confirmed that biomass organic carbon content was the principal sorbent factor affecting OP sorption. For a given sorbent, correlation of the extent of sorption with sorbate chemical properties was examined. Column leaching experiments involving different masses of coconut husk and peanut shell pre-spiked with OPs at the level equivalent to actual spraying concentrations in some Thai tangerine orchards were conducted. These experiments included repeated spikings and leaching. A water flow rate of 20 mL min~(-1) was employed corresponding to the current average watering regime. Retardation and biodegradation with these sorbents were also examined.
机译:用四种不同类型的生物量研究了有机磷(OP)农药毒死rif,普罗诺磷,甲基对硫磷和马拉硫磷的吸附和浸出:椰子壳,稻壳,泥炭藓和花生壳。生物质的有机碳含量在35.4-45.4%的范围内。吸附研究是通过分批(平衡)方法在4种不同的OP峰浓度和pH 3-7下进行的。吸附等温线符合线性Freundlich方程,并且Freundlich常数或吸附系数(K_D)证实生物量有机碳含量是影响OP吸附的主要吸附因子。对于给定的吸附剂,检查了吸附程度与吸附剂化学性质的相关性。进行了柱浸试验,涉及到不同质量的椰子皮和花生壳预加OP的量,其水平相当于一些泰国橘园中的实际喷洒浓度。这些实验包括重复的加标和浸出。对应当前平均浇水方式,采用20 mL min〜(-1)的水流量。还研究了这些吸附剂的延迟和生物降解。

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