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首页> 外文期刊>Journal of Environmental Science and Health >Treatment of high strength olive mill wastewater by Fenton's reagent and aerobic biological process
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Treatment of high strength olive mill wastewater by Fenton's reagent and aerobic biological process

机译:Fenton试剂和好氧生物工艺处理高强度橄榄磨废水

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摘要

The present work describes the application of a Fenton's reagent pretreatment combined with an aerobic biological process to remove the olive mill wastewater (OMW) pollutant load. Wastewater treatment was monitored by means of global parameters directly related to the concentration of organic compounds in OMW effluents: chemical oxygen demand (COD) and total phenolic content (TP). The biologic treatment itself allowed conversions from 67 to 83% of COD and 55 to 61% of TP. In the Fenton's reagent process a fixed H_2O_2/COD ratio of 0.20, a pH = 3.5 and a H_2O_2/Fe~(2+) molar ratio of 15 were defined as optimal conditions to treat the OMW. For an initial COD load of 92.5 g/L~(-1)) the Fenton reagent-biologic combined process allowed a global removal of 80.7% COD and 93.7% TP. A kinetic study was performed resorting to the Grau model. The application of this model allowed observing an increase in the kinetic constant of the combined process (k_FB = 24.7 g/L~(-1) day) when compared to the single aerobic process (k_B = 19.4 g/L~(-1) day).
机译:本工作描述了Fenton试剂预处理与好氧生物工艺相结合的应用,以去除橄榄磨坊废水(OMW)的污染物。通过与OMW废水中有机化合物的浓度直接相关的全局参数来监控废水处理:化学需氧量(COD)和总酚含量(TP)。生物处理本身可以使化学需氧量转化为67%至83%,总磷转化率为55%至61%。在芬顿试剂工艺中,固定的H_2O_2 / COD比为0.20,pH = 3.5和H_2O_2 / Fe〜(2+)摩尔比为15被定义为处理OMW的最佳条件。对于92.5 g / L〜(-1)的初始COD负载量,Fenton试剂-生物法联合工艺可整体去除80.7%的COD和93.7%的TP。依靠Grau模型进行了动力学研究。与单个有氧过程(k_B = 19.4 g / L〜(-1)相比,该模型的应用允许观察到组合过程的动力学常数(k_FB = 24.7 g / L〜(-1)天)的增加。天)。

著录项

  • 来源
    《Journal of Environmental Science and Health》 |2013年第8期|954-962|共9页
  • 作者单位

    Centra de Quimica de Vila Real, Universidade de Tras-os-Montes e Alto Douro (UTAD), Apartado 1013, 5001-801, Vila Real, Portugal;

    Universidad de Extremadura, Departamento de Ingenieria Quimica y Quimica Fisica, Badajoz, Spain;

    Universidad de Extremadura, Departamento de Ingenieria Quimica y Quimica Fisica, Badajoz, Spain;

    Grupo de Catalisis y Procesos de Separation (CyPS), Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Madrid, Spain;

    Centro de Quimica de Vila Real, Universidade de Tras-os-Montes e Alto Douro (UTAD), Vila Real, Portugal;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Olive mill effluent; chemical oxidation; biological treatment; combined Fenton-biologic treatment; Grau model kinetic study;

    机译:橄榄磨坊废水;化学氧化生物处理芬顿联合生物治疗;Grau模型动力学研究;

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