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首页> 外文期刊>Journal of Hazardous Materials >Adsorption of gas-phase elemental mercury by sulphonitrided steel sheet. Effect of hydrogen treatment
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Adsorption of gas-phase elemental mercury by sulphonitrided steel sheet. Effect of hydrogen treatment

机译:硫氮化钢板吸附气相元素汞。氢处理的效果

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摘要

Coal combustion, which is one of the most important energy sources of electricity generation, produces airborne pollutants: NOx, CO2, SO2, particulates and Hg degrees. A range of technologies is being developed to reduce the environmental impact of coal-fired power stations. No optimal technology that can be broadly applied exists as yet, but sorption of mercury is considered a promising approach. We report a novel adsorbent, which shows an extraordinary mechanical resistance and high adsorption capacity of mercury vapour. These adsorbent samples were synthesized in the gas sulphonitriding process using steel sheets. The chemisorption capacity of the sorbent materials, the process of the thermal desorption of mercury and the effect of the hydrogen activation treatment have been investigated in the work. It has been established that the capacity of mercury chemisorption increased more than twice after the heating treatment of the adsorbent in H-2 atmosphere at 500 degrees C in comparison with the non-activated one. The mechanism of activation has been elucidated in the paper. For the purpose of comparison, activated carbon was also investigated.
机译:煤炭燃烧是最重要的发电能源之一,会产生空气中的污染物:NOx,CO2,SO2,颗粒物和汞度。正在开发一系列技术来减少燃煤电站对环境的影响。尚无可广泛应用的最佳技术,但汞吸附被认为是一种有前途的方法。我们报告了一种新型吸附剂,该吸附剂显示出非凡的机械强度和汞蒸气的高吸附能力。这些吸附剂样品是在气相硫氮化工艺中使用钢板合成的。在工作中已经研究了吸附剂材料的化学吸附能力,汞的热脱附过程以及氢活化处理的效果。已经确定,与未活化的汞相比,在H-2气氛中于500℃对吸附剂进行热处理后,汞化学吸附的容量增加了两倍以上。激活的机制已在论文中阐明。为了比较,还研究了活性炭。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2019年第15期|722-731|共10页
  • 作者单位

    Lodz Univ Technol, Gen & Ecol Chem, Zeromskiego 116, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Gen & Ecol Chem, Zeromskiego 116, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Gen & Ecol Chem, Zeromskiego 116, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Gen & Ecol Chem, Zeromskiego 116, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Gen & Ecol Chem, Zeromskiego 116, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Inst Mat Sci & Engn, Stefanowskiego 1-15, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Inst Mat Sci & Engn, Stefanowskiego 1-15, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Inst Mat Sci & Engn, Stefanowskiego 1-15, PL-90924 Lodz, Poland;

    Lodz Univ Technol, Inst Turbomachinery, Wolczanska 219-223, PL-90924 Lodz, Poland;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Mercury emission reduction; Mercury chemisorption; Sulphonitrided sorbent;

    机译:减少汞排放;汞的化学吸附;磺化吸附剂;

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