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首页> 外文期刊>Journal of Hazardous Materials >Bioinspired synthesis of fiber-shaped silk fibroin-ferric oxide nanohybrid for superior elimination of antimonite
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Bioinspired synthesis of fiber-shaped silk fibroin-ferric oxide nanohybrid for superior elimination of antimonite

机译:Bioinspired的纤维状丝素素 - 铁氧化物纳米冬冬嗜酸剂的合成,用于优异的锑酸盐

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摘要

Bioinspired fibrous materials have emerged as a unique class of matrix for fabrication of fiber-shaped nano material assemblies. Here, we report a novel functional fiber-shaped nanohybrid for efficient removal of antimonite via in situ synthesis of ferric oxides anchored to silk nanofibril. The silk nanofibril matrix played important roles in the growth of ferric oxides via metal-ligand interactions. The achieved nanocomposites had high surface areas and activity with more functional groups, contributing to superior antimonite elimination. The nanocomposite achieved a maximum removal capacity of 159.9 mg/g toward antimonite. And the common interfering ions of SO42-, NO3-, CO32- , PO43- and SiO32- exhibited negligible influence on antimonite removal. The mechanism study point that two factors are closely involved: surface complexation and hydrogen bonding. Benefiting from the low cost and environmental-friendly nature of silk fibroin as well as excellent removal capacity and high selectivity, it suggests that the nanohybrids might be promising for antimonite extraction from contaminated water.
机译:Bioinspired纤维材料已成为一种独特的基质,用于制造纤维状纳米材料组件。在这里,我们报告了一种新型功能性纤维状纳米嗜含量,以通过原位合成锚定丝纳米纤维的氧化铁的锑石通过锑岩进行高效去除。丝纳米纤维基质通过金属 - 配体相互作用在氧化铁的生长中发挥了重要作用。达到的纳米复合材料具有高表面积和具有更多官能团的活性,有助于优异的锑石消除。纳米复合材料达到锑矿的最大去除能力为159.9mg / g。和SO42-,NO3-,CO32-,PO43和SiO32的常见干扰离子对锑酸盐除去可忽略不计的影响。机制研究点认为,两个因素密切相关:表面络合和氢键。有益于丝素蛋白的低成本和环保性质以及优异的去除能力和高选择性,表明纳米冬小麦可能是对来自受污染水的锑矿提取的承诺。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2021年第3期|123909.1-123909.7|共7页
  • 作者单位

    Qingdao Univ Inst Marine Biobased Mat Collaborat Innovat Ctr Marine Biobased Fibers & E State Key Lab Biofiber & Ecotext Coll Mat Sci & E 308 Ningxia Rd Qingdao 266071 Peoples R China;

    Qingdao Univ Inst Marine Biobased Mat Collaborat Innovat Ctr Marine Biobased Fibers & E State Key Lab Biofiber & Ecotext Coll Mat Sci & E 308 Ningxia Rd Qingdao 266071 Peoples R China;

    Qingdao Univ Inst Marine Biobased Mat Collaborat Innovat Ctr Marine Biobased Fibers & E State Key Lab Biofiber & Ecotext Coll Mat Sci & E 308 Ningxia Rd Qingdao 266071 Peoples R China;

    Yantai Univ Sch Chem & Chem Engn Yantai 264005 Peoples R China|Univ Florida Dept Chem Engn Gainesville FL 32611 USA;

    Qingdao Univ Coll Chem & Chem Engn Qingdao 266071 Peoples R China;

    Qingdao Univ Inst Marine Biobased Mat Collaborat Innovat Ctr Marine Biobased Fibers & E State Key Lab Biofiber & Ecotext Coll Mat Sci & E 308 Ningxia Rd Qingdao 266071 Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Silk nanofibril/ferric oxide nanohybrids; Advanced antimonite capturing; High selectivity;

    机译:丝纳米纤维/铁氧化物纳米混合;先进的锑矿捕获;高选择性;

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