Thermal behaviour of acrylonitrile polymerization and polyacrylonitrile decomposition

M. Surianarayanan; S. Panduranga Rao; R. Vijayaraghavan

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Thermal behaviour of acrylonitrile polymerization and polyacrylonitrile decomposition

机译：丙烯腈聚合和聚丙烯腈分解的热行为

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The microcalorimetric studies on the polymerization of acrylonitrile with and without the thermal influence of polyacrylonitrile decomposition provide vital information on its thermal ensitivity and intrinsic safety. The present studies indicate that the exothermicity of polymeriza- tion and decomposition of polyacrylonitrile are kept under check by the self-regulatory role of the aqueous medium. However, the polymer drying operation is more prone to thermal hazards under unregulated temperature regime.

机译：在有和没有聚丙烯腈分解热影响的情况下，丙烯腈聚合的微量量热研究提供了有关其热敏性和本质安全性的重要信息。本研究表明，聚丙烯酸酯的聚合反应和放热反应受水性介质的自调节作用控制。然而，在不受调节的温度条件下，聚合物干燥操作更容易产生热危害。

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来源
《Journal of Hazardous Materials》 |1998年第2期|p.187-197|共11页
作者
M. Surianarayanan; S. Panduranga Rao; R. Vijayaraghavan;
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作者单位

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类工程基础科学;
关键词
Thermal sensitivity; Polymerization; Product decomposition;

机译：热敏性;聚合;产品分解;

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Thermal behaviour of acrylonitrile polymerization and polyacrylonitrile decomposition

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