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首页> 外文期刊>Journal of Hazardous Materials >An environmental forensic procedure to analyse anthropogenic pressures of urban origin on surface water of protected coastal agro-environmental wetlands (L'Albufera de Valencia Natural Park, Spain)
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An environmental forensic procedure to analyse anthropogenic pressures of urban origin on surface water of protected coastal agro-environmental wetlands (L'Albufera de Valencia Natural Park, Spain)

机译:一种环境取证程序,用于分析受保护的沿海农业环境湿地的地表水上城市起源的人为压力(西班牙阿尔瓦费拉·德巴伦西亚自然公园)

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摘要

Detection and spatial distribution of 14 drugs of abuse and 17 Pharmaceuticals in surface waters was investigated to determine transport hydrological connectivity between urban, agriculture and natural environments. Solid-phase extraction and liquid chromatography tandem mass spectrometry was applied to all samples. To determine spatial incidence of contaminants, analytical results of target compounds were georeferenced and integrated into a geographical information systems structure together with layers of municipal population, location of sewage water treatment plants and irrigation channels and sectors. The methodology was applied to L'Albufera Natural Park in Valencia (Spain). A total of 9 drugs of abuse were detected at 16 points (76% of the sample sites). Cocaine and its metabolite, benzoylecgo-nine, were the most detected substances, being found in 12 and 16 samples, respectively. Maximum concentrations were found in benzoylecgonine (78.71 ng/L) and codeine (51.60 ng/L). Thirteen pharma-ceuticals were found at 16 points. The most detected compounds were carbamazepine (15 samples) and ibuprofen (11 samples). Maximum concentrations were detected in acetaminophen (17,699.4 ng/L), ibuprofen (3913.7 ng/L) and codeine (434.0 ng/L). Spatial distribution of Pharmaceuticals showed a clear relationship between irrigation areas, high population densities municipalities (above 1000h/km~2) and sewage water treatment plants.
机译:调查了地表水中14种滥用药物和17种药物的检测和空间分布,以确定城市,农业与自然环境之间的运输水文连通性。固相萃取和液相色谱串联质谱法适用于所有样品。为了确定污染物的空间发生率,对目标化合物的分析结果进行了地理配准,并与市政人口,污水处理厂的位置以及灌溉渠道和部门一起,整合到了地理信息系统结构中。该方法已应用于西班牙巴伦西亚的L'Albufera自然公园。在16个点共检测到9种滥用药物(占样本位置的76%)。可卡因及其代谢产物苯甲酰基-羊肉碱是检出率最高的物质,分别在12和16个样品中被发现。苯甲酰芽子碱(78.71 ng / L)和可待因(51.60 ng / L)中发现最大浓度。在16个点发现了13种药品。检出率最高的化合物是卡马西平(15个样品)和布洛芬(11个样品)。在对乙酰氨基酚(17,699.4 ng / L),布洛芬(3913.7 ng / L)和可待因(434.0 ng / L)中检测到最大浓度。药品的空间分布表明灌溉地区,高人口密度的城市(1000h / km〜2以上)和污水处理厂之间有着明确的关系。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2013年第1期|214-223|共10页
  • 作者单位

    Centra de Investigaciones sobre Desertificacion-CSIC-UV-GV, Departamento de Degradation y Conservation de Suelos, Carretera de Moncada-Naquera km 4.5,46115 Moncada, Valencia, Spain;

    Centra de Investigaciones sobre Desertificacion-CSIC-UV-GV, Departamento de Degradation y Conservation de Suelos, Carretera de Moncada-Naquera km 4.5,46115 Moncada, Valencia, Spain;

    Laboratori de Nutricio i Bromatologia, Facultat de Farmacia, Universitar de Valencia, Av. Vicent Andres Estelles s, 46100 Burjassot, Valencia, Spain;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Emerging contaminants; Geographical information systems; Environmental mass spectrometry; Water quality; Mediterranean marshlands;

    机译:新兴污染物;地理信息系统;环境质谱法;水质;地中海沼泽地;

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