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Removal of petroleum sulfonate from aqueous solutions using freshly generated magnesium hydroxide

机译:使用新鲜生成的氢氧化镁从水溶液中去除石油磺酸盐

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摘要

Freshly generated magnesium hydroxide (FGMH), produced by adding water-soluble magnesium salts to highly alkaline solutions, was used to remove anionic surfactant petroleum sulfonate (PS) from aqueous solutions. Adsorption experiments were carried out to investigate the effects of pH, adsorbent dosage, contact time, PS concentration, and temperature. The results showed that FGMH displayed excellent treatment efficiency for PS in the pH range 12.0-13.0. The maximum PS removal efficiency was reached within 60 s. The best dosage of magnesium chloride was 2.0 g/L. The adsorption capacity of FGMH for PS decreased as the temperature increased from 303 K to 333 K. The adsorption process was exothermic. The removal mechanism of PS by FGMH may be a coagulation-adsorption process involving a combination of flocculation, adsorption, charge neutralization, and netting catch affection. The results of this study showed that FGMH can be effectively used to treat surfactant wastewaters.
机译:通过将水溶性镁盐添加到高碱性溶液中而产生的新鲜产生的氢氧化镁(FGMH)用于从水溶液中去除阴离子表面活性剂石油磺酸盐(PS)。进行吸附实验以研究pH,吸附剂用量,接触时间,PS浓度和温度的影响。结果表明,FGMH在12.0-13.0的pH范围内对PS表现出优异的处理效率。在60秒内达到了最大的PS去除效率。氯化镁的最佳剂量为2.0 g / L。随着温度从303 K增加到333 K,FGMH对PS的吸附能力下降。吸附过程是放热的。 FGMH去除PS的机理可能是凝结-吸附过程,涉及絮凝,吸附,电荷中和和结网捕获效应的组合。这项研究的结果表明,FGMH可有效地处理表面活性剂废水。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2012年第15期|p.82-88|共7页
  • 作者单位

    Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse. School of Environmental Science & Engineering. Shandong University, Jinan, China;

    Key Laboratory of Colloid & Interface Science of Education Ministry, Shandong University, Jinan, China;

    Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse. School of Environmental Science & Engineering. Shandong University, Jinan, China;

    Key Laboratory of Colloid & Interface Science of Education Ministry, Shandong University, Jinan, China;

    Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse. School of Environmental Science & Engineering. Shandong University, Jinan, China;

    Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse. School of Environmental Science & Engineering. Shandong University, Jinan, China;

    Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse. School of Environmental Science & Engineering. Shandong University, Jinan, China;

    Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse. School of Environmental Science & Engineering. Shandong University, Jinan, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    freshly generated magnesium hydroxide; petroleum sulfonate; coagulation-adsorption; adsorption isotherms; freundlich model;

    机译:新鲜产生的氢氧化镁;石油磺酸盐凝结吸附吸附等温线弗氏模型;

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